Goldschmidt classification

The Goldschmidt classification,^[1] developed by Victor Goldschmidt, is a geochemical classification which groups the chemical elements according to their preferred host phases into lithophile (rock-loving), siderophile (iron-loving), chalcophile (ore-loving or chalcogen-loving), and atmophile (gas-loving) or volatile (the element, or a compound in which it occurs, is liquid or gaseous at ambient surface conditions).

Some elements have affinities to more than one phase. The main affinity is given in the table below and a discussion of each group follows that table.

Lithophile elements

Lithophile elements are those that remain on or close to the surface because they combine readily with oxygen, forming compounds that do not sink into the core. The lithophile elements include: Al, At, B, Ba, Be, Br, Ca, Cl, Cr, Cs, F, I, Hf, K, Li, Mg, Na, Nb, O, P, Rb, Sc, Si, Sr, Ta, Tc, Th, Ti, U, V, Y, Zr, W and the lanthanides.

Lithophile elements mainly consist of the highly reactive metals of the s- and f-blocks. They also include a small number of reactive nonmetals, and the more reactive metals of the d-block such as titanium, zirconium and vanadium. Lithophile derives from "lithos" which means "rock", and "phile" which means "love".

Most lithophile elements form very stable ions with an electron configuration of a noble gas (sometimes with additional f-electrons). The few that do not, such as silicon, phosphorus and boron, form extremely strong covalent bonds with oxygen – often involving pi bonding. Their strong affinity for oxygen causes lithophile elements to associate very strongly with silica, forming relatively low-density minerals that thus float to the crust. The more soluble minerals formed by the alkali metals tend to concentrate in seawater or extremely arid regions where they can crystallise. The less soluble lithophile elements are concentrated on ancient continental shields where all soluble minerals have been weathered.

Because of their strong affinity for oxygen, most lithophile elements are enriched in the Earth's crust relative to their abundance in the solar system. The most reactive s- and f-block metals, which form either saline or metallic hydrides, are known to be extraordinarily enriched on Earth as a whole relative to their solar abundances. This is because during the earliest stages of the Earth's formation the reaction that controlled the stable form of each chemical element was its ability to form compounds with hydrogen. Under these conditions, the s- and f-block metals were strongly enriched during the formation of the Earth. The most enriched elements are rubidium, strontium and barium, which between them account for over 50 percent by mass of all elements heavier than iron in the Earth's crust.

The nonmetallic lithophiles – phosphorus and the halogens – exist on Earth as ionic salts with s-block metals in pegmatites and seawater. With the exception of fluorine, whose hydride forms hydrogen bonds and is therefore of relatively low volatility, these elements have had their concentrations on Earth significantly reduced through escape of volatile hydrides during the Earth's formation. Although they are present in the Earth's crust in concentrations quite close to their solar abundances, phosphorus and the heavier halogens are probably significantly depleted on Earth as a whole relative to their solar abundances.

Several transition metals, including chromium, molybdenum, iron and manganese, show both lithophile and siderophile characteristics and can be found in both these two layers. Although these metals form strong bonds with oxygen and are never found in the Earth's crust in the free state, metallic forms of these elements are thought very likely to exist in the core of the earth as relics from when the atmosphere did not contain oxygen. Like the "pure" siderophiles, these elements are considerably depleted in the crust relative to their solar abundances.

Owing to their strong affinity for oxygen, lithophile metals, although they form the great bulk of the metallic elements in Earth's crust, were never available as free metals before the development of electrolysis. With this development, many lithophile metals are of considerable value as structural metals (magnesium, aluminium, titanium, vanadium) or as reducing agents (sodium, magnesium, calcium). The process of smelting these metals is extremely energy-intensive. With emissions of greenhouse gases suspected of contributing to climate change, the use of these elements as industrial metals is called into question, despite the depletion of rarer and less reactive chalcophile metals leaving few substitutes.

The non-metals phosphorus and the halogens were also not known to early chemists, though production of these elements is less difficult than of metallic lithophiles since electrolysis is required only with fluorine. Elemental chlorine is particularly important as an oxidizing agent – usually being made by electrolysis of sodium chloride.

Siderophile elements

Abundance (atom fraction) of the chemical elements in Earth's upper continental crust as a function of atomic number. The rarest elements in the crust (shown in yellow) are not the heaviest, but are rather the siderophile (iron-loving) elements in the Goldschmidt classification of elements. These have been depleted by being relocated deeper into the Earth's core. Their abundance in meteoroid materials is relatively higher. Additionally, tellurium and selenium have been depleted from the crust due to formation of volatile hydrides.

Siderophile (from sideron, "iron", and philia, "love") elements are the high-density transition metals which tend to sink into the core because they dissolve readily in iron either as solid solutions or in the molten state.

The siderophile elements include gold, cobalt, iron, iridium, manganese, molybdenum, nickel, osmium, palladium, platinum, rhenium, rhodium and ruthenium.

Most siderophile elements have practically no affinity whatsoever for oxygen: indeed oxides of gold are thermodynamically unstable with respect to the elements. They form stronger bonds with carbon or sulfur, but even these are not strong enough to separate out with the chalcophile elements. Thus, siderophile elements are bound through metallic bonds with iron in the dense layer of the Earth's core where pressures may be high enough to keep the iron solid. Manganese, iron and molybdenum do form strong bonds with oxygen but in the free state (as they existed on the primitive earth when free oxygen did not exist) can mix so easily with iron that they do not concentrate in the siliceous crust as do true lithophile elements. However, ores of manganese are found in much the same sites as are those of aluminium and titanium owing to manganese's great reactivity towards oxygen.

Because they are so concentrated in the dense core, siderophile elements are known for their rarity in the Earth's crust. Most of them have always been known as precious metals because of this. Iridium is the rarest transition metal occurring within the Earth's crust, with an abundance by mass of less than one part per billion. Mineable deposits of precious metals usually form as a result of the erosion of ultramafic rocks, but are not highly concentrated even compared to their crustal abundances, which are typically several orders of magnitude below their solar abundances. However, because they are concentrated in the mantle and core, siderophile elements are believed to be present in the Earth as a whole (including the core) in something approaching their solar abundances.

Chalcophile elements

The chalcophile elements include: Ag, As, Bi, Cd, Cu, Ga, Ge, Hg, In, Pb, Po, S, Sb, Se, Sn, Te, Tl and Zn.

Chalcophile elements are those that remain on or close to the surface because they combine readily with sulfur and/or some other chalcogen other than oxygen, forming compounds which do not sink into the core.

Chalcophile elements are those metals (sometimes called "poor metals") and heavier nonmetals that have a low affinity for oxygen and prefer to bond with sulfur as highly insoluble sulfides. Chalcophile derives from Greek khalkós (χαλκός), meaning "ore" (it also meant "bronze" or "copper", but in this case "ore" is the relevant meaning), and is taken to mean "chalcogen-loving" by various sources.

Because these sulfides are much denser than the silicate minerals formed by lithophile elements, chalcophile elements separated below the lithophiles at the time of the first crystallisation of the Earth's crust. This has led to their depletion in the Earth's crust relative to their solar abundances, though because the minerals they form are nonmetallic, this depletion has not reached the levels found with siderophile elements.

However, because they formed volatile hydrides on the primitive Earth when the controlling redox reaction was the oxidation or reduction of hydrogen, the less metallic chalcophile elements are strongly depleted on Earth as a whole relative to cosmic abundances. This is most especially true of the chalcogens selenium and tellurium, which for this reason are among the rarest elements found in the Earth's crust (to illustrate, tellurium is only about as abundant as platinum).

The most metallic chalcophile elements (of the copper, zinc and boron groups) may mix to some degree with iron in the Earth's core. They are not likely to be depleted on Earth as a whole relative to their solar abundances since they do not form volatile hydrides. Zinc and gallium are somewhat "lithophile" in nature because they often occur in silicate or related minerals and form quite strong bonds with oxygen. Gallium, notably, is sourced mainly from bauxite, an aluminum hydroxide ore in which gallium ion substitutes for chemically similar aluminum.

Although no chalcophile element is of high abundance in the Earth's crust, chalcophile elements constitute the bulk of commercially important metals. This is because, whereas lithophile elements require energy-intensive electrolysis for extraction, chalcophiles can be easily extracted by reduction with coke, and chalcophiles' geochemical concentration – which in extreme cases can exceed 100,000 times average crustal abundance. These greatest enrichments occur in high plateaux like the Tibetan Plateau and the Bolivian altiplano where large quantities of chalcophile elements have been uplifted through plate collisions. A side-effect of this in modern times is that the rarest chalcophiles (like mercury) are so completely exploited that their value as minerals has almost completely disappeared.

Atmophile elements

The atmophile elements are: H, C, N and the noble gases.

Atmophile elements (also called "volatile elements") are defined as those that remain mostly on or above the surface because they are, or occur in, liquids and/or gases at temperatures and pressures found on the surface. The noble gases do not form stable compounds and occur as monatomic gases, while nitrogen, although it does not have a stable configuration for its individual atoms, forms a diatomic molecule so strong that all oxides of nitrogen are thermodynamically unstable with respect to nitrogen and oxygen. Consequently, with the development of free oxygen through photosynthesis, ammonia was oxidised to molecular nitrogen which has come to form four-fifths of the Earth's atmosphere. Carbon is also classed as an atmophile because it forms very strong multiple bonds with oxygen in carbon monoxide (slowly oxidised in the atmosphere) and carbon dioxide. The latter is the fourth-largest constituent of the Earth's atmosphere, while carbon monoxide occurs naturally in volcanoes and has a residence time in the atmosphere of a few months.

Hydrogen, which occurs in the compound water, is also classed as an atmophile. Water is classified as a volatile, because most of it is liquid or gas, even though it does exist as a solid compound on the surface.

Because all atmophile elements are either gases or form volatile hydrides, atmophile elements are strongly depleted on earth as a whole relative to their solar abundances owing to losses from the atmosphere during the formation of the Earth. The heavier noble gases (krypton, xenon) are the rarest stable elements on Earth.

See also

• Abundance of the chemical elements
• Victor Goldschmidt
• Goldschmidt Tolerance Factor

References

External links

• Mineralogy notes 3
• W. M. White. Geochemistry. ISBN 978-0470656686; Chapter 7.2