Dithiolane
From Wikipedia, the free encyclopedia
Dithiolane | ||
---|---|---|
IUPAC name Dithiolane | ||
Other names 1,2-dithiolane, 1,3-dithiolane | ||
Identifiers | ||
PubChem | 79045 | |
ChemSpider | 71377 | |
ChEBI | CHEBI:38226 | |
Jmol-3D images | Image 1 | |
| ||
| ||
Properties | ||
Molecular formula | C3H6S2 | |
Related compounds | ||
Related compounds | 1,2-Ethanedithiol | |
(verify) (what is: / ?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa) | ||
Infobox references | ||
A dithiolane is a sulfur heterocycle derived from cyclopentane by replacing two methylene bridges (-CH
2- units) with thioether groups. The parent compounds are 1,2-dithiolane and 1,3-dithiolane.
1,2-Dithiolanes, such as lipoic acid, are cyclic disulfides.
1,3-Dithiolanes are important as protecting groups for carbonyl compounds, since they are inert to a wide range of conditions. Reacting a carbonyl group with 1,2-ethanedithiol converts it to a 1,3-dithiolane, as detailed below.
External links
This article is issued from Wikipedia. The text is available under the Creative Commons Attribution/Share Alike; additional terms may apply for the media files.