Curie
The curie (symbol Ci) is a non-SI unit of radioactivity, named after Marie and Pierre Curie.[1][2] It is defined as
While its continued use is discouraged by NIST[3] and other bodies, the curie is widely used throughout the US government and industry.
One curie is roughly the activity of 1 gram of the radium isotope 226Ra, a substance studied by the Curies.
The SI derived unit of radioactivity is the becquerel (Bq), which equates to one decay per second. Therefore:
- 1 Ci = 3.7 × 1010 Bq = 37 GBq
and
- 1 Bq ≅ 2.703 × 10−11 Ci
Another commonly used measure of radioactivity is the microcurie:
- 1 μCi = 3.7 × 104 disintegrations per second = 2.22 × 106 disintegrations per minute
A radiotherapy machine may have roughly 1000 Ci of a radioisotope such as caesium-137 or cobalt-60. This quantity of radioactivity can produce serious health effects with only a few minutes of close-range, unshielded exposure.
Ingesting even a millicurie is usually fatal (unless it is a very short-lived isotope). For example, the LD-50 for ingested polonium-210 is 240 μCi.
The typical human body contains roughly 0.1 μCi (14 mg) of naturally occurring potassium-40. A human body containing 16 kg of carbon (see Composition of the human body) would also have about 24 nanograms or 0.1 μCi of carbon-14. Together, these would have an activity of approximately 2×0.1 μCi or 7400 decays (mostly from beta decay and rarely from gamma decay) per second inside the person's body.
Curies as a measure of quantity
Curies are occasionally used to express a quantity of radioactive material rather than a decay rate, such as when one refers to 1 Ci of caesium-137. This may be interpreted as the number of atoms that would produce 1 Ci of radiation. The rules of radioactive decay may be used convert this to an actual number of atoms. They state that 1 Ci of radioactive atoms would follow the expression:
- N (atoms) × λ (s−1) = 1 Ci = 3.7 × 1010 (Bq)
and so,
- N = 3.7 × 1010 / λ,
where λ is the decay constant in (s−1).
We can also express a Curie in moles:
- Failed to parse(unknown function '\begin'): {\begin{aligned}{\text{1 Ci}}&={\frac {3.7\times 10^{{10}}}{(\ln 2)N_{{{\rm {A}}}}}}{\text{ moles}}\times t_{{1/2}}{\text{ in seconds}}\\&\approx 8.8639\times 10^{{-14}}{\text{ moles}}\times t_{{1/2}}{\text{ in seconds}}\\&\approx 5.3183\times 10^{{-12}}{\text{ moles}}\times t_{{1/2}}{\text{ in minutes}}\\&\approx 3.1910\times 10^{{-10}}{\text{ moles}}\times t_{{1/2}}{\text{ in hours}}\\&\approx 7.6584\times 10^{{-9}}{\text{ moles}}\times t_{{1/2}}{\text{ in days}}\\&\approx 2.7972\times 10^{{-6}}{\text{ moles}}\times t_{{1/2}}{\text{ in years}}\end{aligned}}
where NA is Avogadro's number and t1/2 is the half life. The number of moles may be converted to grams by multiplying by the atomic mass.
Here are some examples:
Isotope | Half life | Mass of 1 Curie |
---|---|---|
238U | 4.471×109 years | 2.977 tonnes |
40K | 1.25×109 years | 140 kg |
129I | 15.7×106 years | 5.66 kg |
99Tc | 211×103 years | 58 g |
239Pu | 24.11×103 years | 16 g |
14C | 5730 years | 0.22 g |
226Ra | 1601 years | 1.01 g |
137Cs | 30.17 years | 12 mg |
90Sr | 28.8 years | 7.2 mg |
60Co | 1925 days | 883 μg |
210Po | 138 days | 223 μg |
131I | 8.02 days | 8 μg |
123I | 13 hours | 0.5 μg |
The number of Curies present in a sample decreases with time because of decay.
See also
- Geiger counter
- Ionizing radiation
- Radiation exposure
- Radiation poisoning
- United Nations Scientific Committee on the Effects of Atomic Radiation
References
- ↑ curie - Britannica Online Encyclopedia
- ↑ Paul W. Frame. "How the Curie Came to Be". Retrieved 2008-04-30.
- ↑ Nist Special Publication 811, paragraph 5.2.