Cumene hydroperoxide

From Wikipedia, the free encyclopedia
Cumene hydroperoxide[1]
Identifiers
CAS number 80-15-9 YesY
PubChem 6629
ChemSpider 6377 YesY
Jmol-3D images Image 1
Properties
Molecular formula C9H12O2
Molar mass 152.19 g mol−1
Appearance colorless to pale yellow liquid
Density 1.02 g/cm3
Melting point −9 °C; 16 °F; 264 K
Boiling point 153 °C
Solubility in water 1.5 g / 100 mL
Vapor pressure 14 mmHg at 20 °C
Hazards
MSDS sigmaaldrich.com
GHS pictograms
GHS signal word DANGER
GHS hazard statements H242, H302, H312, H314, H331, H373, H411
GHS precautionary statements P220, P261, P273, P280, P305+351+338, P310
NFPA 704
2
1
4
Flash point 57 °C; 135 °F; 330 K
 YesY (verify) (what is: YesY/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
Infobox references

Cumene hydroperoxide is an intermediate in the cumene process for developing phenol and acetone from benzene and propylene. It is typically used as an oxidizing agent.[2] Products of decomposition of cumene hydroperoxide are methylstyrene, acetophenone and cumyl alcohol.[3] Its formula is C6H5C(CH3)2OOH.

One of the key uses for the material is as a free radical initiator for acrylate and methacrylates monomers.

References

  1. University, Safety Officer in Physical Chemistry at Oxford (2005). "Safety (MSDS) data for cumene hydroperoxide". Retrieved 2009-05-13 
  2. Richard J. Lewis, Richard J. Lewis (Sr.), Hazardous chemicals desk reference, Publisher Wiley-Interscience, 2008, ISBN 0-470-18024-2, ISBN 978-0-470-18024-2, 1953 pages (page 799)
  3. Cumene Hydroperoxide at the Organic Chemistry Portal

Related terms

External links

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