Cobalt(II) oxide
| Cobalt(II) oxide | |
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| IUPAC name Cobalt(II) oxide | |
| Other names Cobaltous oxide | |
| Identifiers | |
| CAS number | 1307-96-6  |
| PubChem | 9942118 |
| ChemSpider | 8117730 |
| EC number | 215-154-6 |
| UN number | 3288 |
| RTECS number | GG2800000 |
| Jmol-3D images | {{#if:[Co]=O[Co+2].[O-2]|Image 1 Image 2 |
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| Properties | |
| Molecular formula | CoO |
| Molar mass | 74.9326 g/mol |
| Appearance | black powder |
| Odor | odorless |
| Density | 6.44 g/cm3 [1] |
| Melting point | 1,933 °C; 3,511 °F; 2,206 K |
| Solubility in water | insoluble in water[2] |
| Structure | |
| Crystal structure | cubic, cF8 |
| Space group | Fm3m, No. 225 |
| Hazards | |
| MSDS | ICSC 1551 |
| EU Index | 027-002-00-4 |
| EU classification | Harmful (Xn) Dangerous for the environment (N) |
| R-phrases | R22, R43, R50/53 |
| S-phrases | (S2), S24, S37, S60, S61 |
| Flash point | Non-flammable |
| LD50 | 202 mg/kg |
| Related compounds | |
| Other anions | Cobalt(II) sulfide Cobalt(II) hydroxide |
| Other cations | Iron(II) oxide Nickel(II) oxide |
| Related compounds | Cobalt(II,III) oxide Cobalt(III) oxide |
(verify) (what is: / ?)Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa) | |
| Infobox references | |
Cobalt(II) oxide or cobalt monoxide is an inorganic compound that appears as olive-green to red crystals, or as a greyish or black powder.[3] It is used extensively in the ceramics industry as an additive to create blue colored glazes and enamels as well as in the chemical industry for producing cobalt(II) salts.
Structure and properties
CoO crystals adopt the periclase (rock salt) structure with a lattice constant of 4.2615 Å.[4]
It is antiferromagnetic below 16 °C.[5]
Preparation
Cobalt(II,III) oxide decomposes to cobalt(II) oxide at 950 °C:[6]
- 2 Co3O4 → 6 CoO + O2
Though commercially available, cobalt(II) oxide may be prepared in the laboratory by electrolyzing a solution of cobalt(II) chloride.[7]
CoCl2 + H2O → CoO + H2 + Cl2
It may also be prepared by precipitating the hydroxide, followed by thermal decomposition:
- CoX + 2 NaOH → Co(OH)2 + Na2X
- Co(OH)2 → CoO + H2O
Reactions
As can be expected, cobalt(II) oxide reacts with mineral acids to form the corresponding cobalt salts:
- CoO + 2 HX → CoX2 + H2O
Applications
Cobalt(II) oxide has for centuries used as a coloring agent on kiln fired pottery. The additive provides a deep shade of blue named cobalt blue. The band gap (CoO) is around 2.4 eV. It also is used in cobalt blue glass.
References
- ↑ Patnaik, Pradyot (2003). Handbook of Inorganic Chemical Compounds. McGraw-Hill. ISBN 0-07-049439-8. Retrieved 2009-06-06.
- ↑ Advanced Search – Alfa Aesar – A Johnson Matthey Company. Alfa.com. Retrieved on 2011-11-19.
- ↑ "Safety (MSDS) data for cobalt oxide". The Physical and Theoretical Chemistry Laboratory, Oxford University. Retrieved 2008-11-11.
- ↑ Kannan, R.; Seehra, Mohindar S. (1987). "Percolation effects and magnetic properties of the randomly diluted fcc system CopMg1-pO". Physical Review B 35 (13): 6847. doi:10.1103/PhysRevB.35.6847.
- ↑ Silinsky, P. S.; Seehra, Mohindar S. (1981). "Principal magnetic susceptibilities and uniaxial stress experiments in CoO". Physical Review B 24: 419. doi:10.1103/PhysRevB.24.419.
- ↑ US 4389339, James, Leonard E.; Crescentini, Lamberto & Fisher, William B., "Process for making a cobalt oxide catalyst"
- ↑ Kern, S. (1876). J. Chem. Soc.: 880.
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