Carbon monosulfide
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| Carbon monosulfide | |
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| IUPAC name carbon monosulfide | |
| Other names carbon(II) sulfide | |
| Identifiers | |
| CAS number | 2944-05-0  |
| PubChem | 108054 |
| ChemSpider | 97157 |
| Jmol-3D images | {{#if:[S+]#[C-]|Image 1 |
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| Properties | |
| Molecular formula | CS |
| Molar mass | 44.08 g mol−1 |
| Appearance | reddish crystalline powder |
| Solubility in water | insoluble |
(verify) (what is: / ?)Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa) | |
| Infobox references | |
Carbon monosulfide is a chemical compound with the formula CS. This diatomic molecule is the sulfur analogue of carbon monoxide, and is unstable as a solid or a liquid, but it has been observed as a gas both in the laboratory and in the interstellar medium.[1] The molecule resembles carbon monoxide with a triple bond between carbon and sulfur. The molecule is not intrinsically unstable, but it tends to polymerize. This tendency reflects the greater stability of C-S single bonds.
Polymers with the formula (CS)n have been reported.[2] Also, CS has been observed as a ligand in certain transition metals.
References
- ↑ Wilson, R. W.; Penzias, A. A.; Wannier, P. G.; Linke, R. A. (1976). "Isotopic abundances in interstellar carbon monosulfide" (pdf). Astrophysical Journal 204 (pt 2): L135–L137. Bibcode:1976ApJ...204L.135W. doi:10.1086/182072.
- ↑ Chou, J.-H.; Rauchfuss, T. B. (1997). "Solvatothermal Routes to Poly(Carbon Monosulfide)s Using Kinetically Stabilized Precursors" (pdf). Journal of the American Chemical Society 119 (19): 4537–4538. doi:10.1021/ja970042w.
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