1,2-Dichloroethene

From Wikipedia, the free encyclopedia
cis-1,2-Dichloroethene (Z) (left) and trans-1,2-Dichloroethene (E) (right)
IUPAC name

1,2-Dichloroethene

Other names

1,2-Dichloroethylene
1,2-DCE

Identifiers
CAS number 156-59-2 (Z) YesY, 156-60-5 (E), 540-59-0 (mixture of E and Z)
PubChem 643833 (Z), 638186 (E), 10900 (mixture of E and Z)
ChemSpider 10438 YesY
KEGG C06792 YesY
ChEBI CHEBI:18882 YesY
Jmol-3D images {{#if:Cl[C@H]=CClClC=CCl|Image 1
Image 2
Properties
Molecular formula C2H2Cl2
Molar mass 96.95 g/mol
Density Z: 1.28 g/cm³
E: 1.26 g/cm³
Melting point Z: -81.47 °C
E: -49.44 °C
Boiling point Z: 60.2 °C
E: 48.5 °C
Dipole moment Z: 1.9 D
E: 0 D
 YesY (verify) (what is: YesY/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
Infobox references

1,2-Dichloroethene, commonly called 1,2-dichloroethylene or 1,2-DCE, is an organochloride with the molecular formula C2H2Cl2. It is a highly flammable, colorless liquid with a sharp, harsh odor. It can exist as either of two geometric isomers, cis-1,2-dichloroethene or trans-1,2-dichloroethene, but is often used as a mixture of the two. They have modest solubility in water. These compounds have "scarcely any industrial applications,"[1] although they are fundamental given their simple stoichiometries.

Production

cis-DCE is obtainable by the controlled chlorination of acetylene:

C2H2 + Cl2 → C2H2Cl2

Industrially both isomers arise as byproduct of the production of vinyl chloride, which is produced on a vast scale. Unlike vinyl chloride, the 1,2-dichloroethylene isomers do not polymerize.[1]

These compounds once were used as solvents, but other chlorocarbons such as dichloromethane are now used.

Safety

These compounds have "moderate oral toxicity to rats."[1]

See also

References

  1. ↑ 1.0 1.1 1.2 E.-L. Dreher, T. R. Torkelson, K. K. Beutel (2011). "Chlorethanes and Chloroethylenes". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.o06_o01. 

External links

This article is issued from Wikipedia. The text is available under the Creative Commons Attribution/Share Alike; additional terms may apply for the media files.