Weddellite

Weddellite
General
Category Organic compounds
Chemical formula Oxalate(Oxalic acid) (Calcium oxalate dihydrate CaC2O4·2H2O )
Strunz classification 10.AB.40
Identification
Color Yellowish brown
Crystal habit eight-face bi-pyramid (typical)
Crystal system Tetragonal
Twinning yes
Cleavage OUI
Fracture Conchoidal
Mohs scale hardness 4
Luster Vitreous (Glassy)
Streak White
Refractive index 1.52-1.54 - DR +0.009 (B-G interval)

Weddellite (CaC2O4·2H2O) is a mineral form of calcium oxalate named for occurrences of millimeter-sized crystals found in bottom sediments of the Weddell Sea, off Antarctica. Occasionally, weddellite partially dehydrates to whewellite, forming excellent pseudomorphs of grainy whewellite after weddellite's short tetragonal dipyramids.

Contents

Structural properties

The weddellite or calcium oxalate di-hydrate crystallizes in the tetragonal system. The classic crystal shape is the eight-face bi-pyramid. In bright field microscopy, the weddellite crystals are recognized easily by their shape that reminds a mail envelope. More complex shapes of weddellite are possible. The dumbbell shape is not rare. The former has no precise angles or sides. This form is, in reality, a microcrystalline agglomerate that takes the shape of a biconcave disc. Weddellite crystals are poorly birefringent and do not show any interference pattern under polarized light.

Biological role

Weddellite crystals are usually of little clinical value. Many specimens develop weddellite crystals on standing. Together, whewellite and weddellite are the most common renal calculi.

Varieties and related minerals

Natroxalate, Whewellite, Caoxite, Novgorodovaite, Oxammite, Glushinskite, Humboldtine, Minguzzite, Zhemchuzhnikovite, Stepanovite, Moolooite, Wheatleyite, Coskrenite

References