Trinitroanisole

Trinitroanisole
Identifiers
CAS number 606-35-9
ChemSpider 15546303 Y
Jmol-3D images Image 1
Properties
Molecular formula C7H5N3O7
Molar mass 243.13 g/mol
Appearance yellow, "leaf-like" crystals
Density 1.408 g/cm3
Melting point

68.4 °C

Boiling point

explodes

Solubility in water insoluble in water, soluble in diethyl ether and hot ethanol
Hazards
Main hazards explosive
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Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Trinitroanisole is a chemical compound that exists as pale yellow crystals with a melting point of 68.4 °C. It is an explosive with a detonation velocity of 7200 meters per second.[1][2]

Synthesis

Trinitroanisole can be prepared by the reaction of 2,4-Dinitrochlorobenzene with methanol in the presence of sodium hydroxide followed by the nitration of the resulting product. Alternatively, it can be prepared directly by the reaction of picryl chloride with methanol in the presence of sodium hydroxide.[1][2]

Use

Historically, trinitroanisole was used as a military explosive, however, due to its tendency to form picric acid and dangerous picrate salts, its use has largely been abandoned.[3]

Notes

  1. ^ a b Wikimedia Foundation."Trinitroanisole", "German Wikipedia", accessed July 21, 2011.
  2. ^ a b Wasag-Chemie, Essen. "Explosives". 1961, p. 164
  3. ^ Wikimedia Foundation. "Tri-nitroanisole", "Japanese Wikipedia", accessed July 21, 2011.