Tetrasodium pyrophosphate

Tetrasodium pyrophosphate
Identifiers
CAS number 7722-88-5 Y, 13472-36-1 (decahydrate)
Properties
Molecular formula Na4O7P2
Molar mass 265.9 g mol−1
Appearance Colorless crystals
Hazards
EU Index Not listed
Flash point Non-flammable
Related compounds
Other anions Trisodium phosphate
Pentasodium triphosphate
Hexasodium metaphosphate
Other cations Tetrapotassium pyrophosphate
Related compounds Disodium pyrophosphate
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Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Tetrasodium pyrophosphate, also called sodium pyrophosphate, tetrasodium phosphate or TSPP, is a colorless transparent crystalline chemical compound with the formula Na4P2O7. It contains the pyrophosphate ion and sodium cation. Toxicity is approximately twice that of table salt when ingested orally.[1] There is also a hydrated form, Na4P2O7 · 10(H2O).[2]

Sodium pyrophosphate is used as a buffering agent, an emulsifier, a dispersing agent, and a thickening agent, and is often used as a food additive. Common foods containing sodium pyrophosphate include chicken nuggets, marshmallows, pudding, crab meat, imitation crab, canned tuna, and soy-based meat alternatives and cat foods and cat treats where it is used as a palatability enhancer. It is the active ingredient in Bakewell, the substitute for baking powder's acid component marketed during shortages in World War II. It is also used in some common baking powders.

In toothpaste and dental floss, sodium pyrophosphate acts as a tartar control agent, serving to remove calcium and magnesium from saliva and thus preventing them from being deposited on teeth.

Sodium pyrophosphate is sometimes used in household detergents to prevent similar deposition on clothing, but due to its phosphate content it causes eutrophication of water, promoting algae growth.

Calcium pyrophosphate is the crystal deposited in joints in the medical condition pseudogout.[3]

References

  1. ^ Handbook of food toxicology, S. S. Deshpande, page 260
  2. ^ D.L. Perry S.L. Phillips (1995) Handbook of inorganic compounds CRC Press ISBN 0-8493-8671-3
  3. ^ Clinical Medicine, Kumar and Clark, 6th Ed., p. 571