Sulfene

Sulfene

Other names Thioformaldehyde-S,S-dioxide
Identifiers
CAS number	917-73-7
PubChem	12244237
ChemSpider	10645700^Y
Jmol-3D images	Image 1
SMILES C=S(=O)=O
InChI InChI=1S/CH2O2S/c1-4(2)3/h1H2^Y Key: LZOZLBFZGFLFBV-UHFFFAOYSA-N^Y InChI=1/CH2O2S/c1-4(2)3/h1H2 Key: LZOZLBFZGFLFBV-UHFFFAOYAF
Properties
Molecular formula	CH₂SO₂
Molar mass	78.090 g mol⁻¹
Exact mass	77.977549998 g mol⁻¹
Structure
Molecular shape	trigonal planar at C and S
Y (verify) (what is: Y/N?) Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Sulfene is an extremely unstable^[1] chemical compound with the formula H₂CSO₂. It is the simplest member of the sulfenes, the group of compounds which are S,S-dioxides of thioaldehydes and thioketones, and have the general formula R₂CSO₂.^[2]

References

^ Ingo-Peter Lorenz (April 1978). "Demonstration of "Sulfene" Insertion into the Metal-Hydrogen Bond". Angewandte Chemie International Edition in English 17 (4): 285–286. doi:10.1002/anie.197802851.
^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "sulfenes".