Suasdlsdjety godovikovite and millosevichite. The outer zone can easily be hydrated giving rise to minerals like tschermigite and alunogen. The zone forms due to interaction with hot (even around 600 °C) coal-derived gases (mainly NH3 and SO3) with the "sterile" material (i.e. shales and other rocks serving as the source of Al3+, Fe3+, Ca2+ and other cations) in case of the lack of vents for the gases to escape into the atmosphere.[1][2][3]