Stock nomenclature

Stock nomenclature for inorganic compounds is a widely used system of chemical nomenclature developed by the German chemist Alfred Stock and first published in 1919. In the 'Stock system', the oxidation states of some or all the elements in a compound are indicated in parentheses by Roman numerals.^[1]^[2]

1 Style
2 Examples
- 2.1 Mixed-valence compounds
3 See also
4 References

Style

Contrary to the usual English style for parentheses, there is no space between the end of the element name and the opening parenthesis: for AgF, the correct style is "silver(I) fluoride" not "silver (I) fluoride".

Where there is no ambiguity about the oxidation state of an element in a compound, it is not necessary to indicate it with Roman numerals: hence for NaCl, sodium chloride will suffice; sodium(I) chloride(−I) is unnecessarily long and such usage is very rare.

Examples

FeCl₂: iron(II) chloride
FeCl₃: iron(III) chloride
K[MnO₄]: potassium manganate(VII) (rarely used except in pre-university education, potassium permanganate is ubiquitous)
[Co(NH₃)₆]³⁺: hexaamminecobalt(III)

Mixed-valence compounds

Co₃O₄: cobalt(II,III) oxide. Co₃O₄ is a mixed-valence compound that is more accurately described as Co^IICo^III₂O₄, i.e. [Co²⁺][Co³⁺]₂[O²⁻]₄.^[3]
Sb₂O₄: antimony(III,V) oxide. Sb₂O₄ is better formulated as Sb^IIISb^VO₄, i.e. [Sb³⁺][Sb⁵⁺][O²⁻]₄.

References

^ Clugston, Michael; Rosalind, Flemming (2000). Advanced Chemistry. Oxford University Press. pp. 214-215. ISBN 9780199146338.
^ Housecroft, C. E.; Sharpe, A. G. (2008). Inorganic Chemistry (3rd ed.). Prentice Hall. p. 213. ISBN 978-0131755536.
^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Oxford: Butterworth-Heinemann. p. 1118. ISBN 0080379419.

Stock nomenclature

Contents

Style

Examples

Mixed-valence compounds

See also

References