Stibole

Stibole
IUPAC name

1H-Stibole
Identifiers
CAS number 288-04-0 N
Jmol-3D images Image 1
Image 2
Properties
Molecular formula C4H5Sb
Molar mass 174.84 g mol−1
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Stibole is a theoretical heterocyclic organic compound, a five-membered ring with the formula C4H4SbH. It is classified as a metallole. It can be viewed as an structural analog of pyrrole, with antimony replacing the nitrogen atom of pyrrole. Substituted derivatives, which have been synthesized, are called stiboles.

Reactions

2,5-Dimethyl-1-phenyl-1H-stibole, for example, can be formed by the reaction of 1,1-dibutyl-2,5-dimethylstannole and dichlorophenylstibine.[1] Stiboles can be used to form ferrocene-like sandwich compounds.[2]

See also

References

  1. ^ J.I.G. Cadogan, S.V. Ley, G. Pattenden, R.A. Raphael, C.W. Rees, ed. (1996), Dictionary of Organic Compounds, 3 (6 ed.), Chapman & Hall, pp. 2710, ISBN 9780412540905, http://books.google.com/books?id=C3Uo1co4Wv0C&pg=PA2710, retrieved 2010-03-04 
  2. ^ A.R. Katritzky, Otto Meth-Cohn, C.W. Rees, ed. (1995), Comprehensive Organic Functional Group Transformations, 4, Elsevier, pp. 1038–1040, ISBN 9780080423258, http://books.google.com/books?id=0RQEsfYCuBcC&pg=PA1038, retrieved 2010-03-04