Sewardite

Sewardite
General
Category Arsenate minerals
Chemical formula CaFe2+3(AsO4)2(OH)2
Strunz classification 08.BH.30
Crystal symmetry Orthorhombic (2/m 2/m 2/m) - dipyramidal
Unit cell a = 16.461 Å, b = 7.434 Å, c = 12.131 Å; Z = 8
Identification
Molar mass 464.68 g
Color Dark red, lighter red orange
Crystal habit Platy, aggregates, anhedral Grains
Crystal system Orthorhombic space group = C ccm
Cleavage {100} and {011} imperfect
Fracture Splintery - thin elongated fractures
Mohs scale hardness 3.5
Luster Vitreous (glassy)
Streak Reddish brown
Diaphaneity Transluscent
Specific gravity 4.16
Optical properties Weak Anistropic
Refractive index 1.94 calculated
Birefringence Weak
Pleochroism None
References [1][2]

Sewardite is a rare arsenate mineral with formula of CaFe2+3(AsO4)2(OH)2.[3] Sewardite was discovered in 1982 and named for the mineralogist, Terry M. Seward (1940-), a professor of geochemistry in Zürich, Switzerland.[3]

Properties

Sewardite is orthorhombic, which means in crystallographic terms, it contains 3 axes of unequal length, one "c" axis, and 1 "a" axis, and 1 "b" axis. The "c" axis runs vertically, and the "b" axis forms a 90 degree angle with the "c" axis; the "a" axis forms an angle that is less than 90 degrees. It's class structure in the crystal system, orthorhombic, is mmm (2/m 2/m 2/m) - dipyramidal. Sewardite can form platy to compact anhedral to subhedral masses up to 0.3 mm in size in a single specimen.[4]

In terms of its optical properties, sewardite is weak anisotropic, which means the velocity of light varies depending on the direction through the mineral. Its color in plane-polarized light is dark red, and it does not exhibit pleochroism, which means it does not appear to be a different color when observed at different angles under a polarizing petrographic microscope. Sewardite illustrates weak birefringence; birefringence is directly dependent on the material being anistropic, so since sewardite is weakly anistropic, it exhibits weak birefringence.[5]

Occurrence

Sewardite has only been found at three locations, in the Tsumeb mine in Tsumeb, Namibia, Mina Ojuela, Mapimi, Durango, Mexico, and La Mur, Las Animas mine, Sonora, Mexico.[2] The Tsumeb Mine is the most prolific mine in the world, and occurs in a geologic setting of the subduction belt of Namibia, which produces the conditions in which sewardite occurs. At the site in Durango, Mexico, it occurs as a dark, reddish spherules and rosettes of very thin, flaky crystals that would be compacted together in sparkling masses.

This newly discovered mineral (confirmed as a species in 1998) has been determined as rare, since only 1-2 mg of it have been found on Earth. Since it's such a rarity, any use found for the mineral would be very impractical due to its existing quantity.[6]

References

  1. ^ "Sewardite Mineral Data." http://webmineral.com/data/Sewardite.shtml. Accessed 30 September 2010.
  2. ^ a b Mindat.org
  3. ^ a b Ralph, Jolyon, and Chau, Idau, 26 July 2010, "Mindat Mineralogy Database." http://www.mindat.org/forum.php?read,85,121470,132995. Accessed 16 September 2010.
  4. ^ Roberts, A.C., Cooper, M.A., Hawthorne, F.C., Criddle, A.J., and Striddle, J.A.R. (2002) Sewardite, CaFe32+(AsO4)2(OH)2, the Ca-analog of carminite, from Tsumeb, Namibia: description and crystal structure. Canadian Mineralogist, 40, 1191-1198.
  5. ^ "Mineral General Info." http://www.mineralatlas.com/mineral%20optical%20descriptions/S/sewarditeopt.htm. Accessed 7 November 2010.
  6. ^ Roberts, Andrew, Cooper, Mark, Hawthorne, Frank, Criddle, Alan, and Stirling, John, 2002, "Sewardite, CaFe3+2(AsO4)2(OH)2, The Ca-Analogue of Carminite, from Tsumeb, Namibia: Description and Crystal Structure." http://rruff.geo.arizona.edu/doclib/cm/vol40/CM40_11. Accessed 22 Nov 2010.