Plutonium-244

Actinides Half-life Fission products
244Cm 241Pu f 250Cf 243Cmf 10–30 y 137Cs 90Sr 85Kr
232 f 238Pu f is for
fissile
69–90 y 151Sm nc➔
4n 249Cf  f 242Amf 141–351 No fission product
has half-life 102
to 2×105 years
241Am 251Cf  f 431–898
240Pu 229Th 246Cm 243Am 5–7 ky
4n 245Cmf 250Cm 239Pu f 8–24 ky
233U    f 230Th 231Pa 32–160
4n+1 234U 4n+3 211–290 99Tc 126Sn 79Se
248Cm 242Pu 340–373 Long-lived fission products
237Np 4n+2 1–2 My 93Zr 135Cs nc➔
236U 4n+1 247Cmf 6–23 My 107Pd 129I
244Pu 80 My >7% >5% >1% >.1%
232Th 238U 235U    f 0.7–12 Gy fission product yield

Plutonium-244 (244Pu) is an isotope of plutonium that has a halflife of 80 million years. This is longer than any of the other isotopes of plutonium and longer than any actinide except for the three naturally abundant ones uranium-235 (700my), uranium-238, and thorium-232. It is also longer than any other known radioactive isotopes except samarium-146 (103my), potassium-40 (1.25by), and a number of nearly stable isotopes with half-lives much longer than the age of the universe, such as bismuth-209 (19 quintillion years).

More accurate measurements, beginning in the early 1970s, have detected primordial plutonium-244.[1] As the age of the Earth is about 50 half-lives, the amount of plutonium-244 left should be very small. However, since plutonium-244 cannot be easily produced by natural neutron capture in the low neutron activity environment of uranium ores (see below), its presence cannot plausibly be explained by any other means than creation by r-process nucleosynthesis in supernovae. Plutonium-244 is thus the shortest-lived and heaviest primordial isotope yet detected or theoretically predicted.

Unlike plutonium-238, plutonium-239, plutonium-240, plutonium-241, and plutonium-242, plutonium-244 is not produced in quantity by the nuclear fuel cycle, because further neutron capture on plutonium-242 produces plutonium-243 which has a short halflife (5 hours) and quickly beta decays to americium-243 before having much opportunity to further capture neutrons in any but very high neutron flux environments. However a nuclear weapon explosion can produce some plutonium-244 by rapid successive neutron capture.

References

  1. ^ D. C. Hoffman, F. O. Lawrence, J. L. Mewherter, F. M. Rourke: "Detection of Plutonium-244 in Nature", in: Nature 1971, 234, 132–134; doi:10.1038/234132a0.