Platinum(IV) bromide

Platinum(IV) bromide
Identifiers
CAS number 68936-92-1
Properties
Molecular formula PtBr4
Molar mass 514.700 g/mol
Appearance brownish-black crystals
Melting point

decomposes at 180°C

Solubility in water 0.41 g/100mL @ 20°C
Solubility slightly soluble in ethanol, diethyl ether[1]
Hazards
MSDS [1]
EU classification Corrosive (C)
R-phrases R34
S-phrases S20, S26, S36/37/39, S45, S60
NFPA 704
0
2
1
Flash point non-flammable
Related compounds
Other anions Platinum(IV) fluoride
Platinum(IV) chloride
Platinum(IV) iodide
Other cations Nickel(II) bromide
Palladium(II) bromide
Platinum(II) bromide
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Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Platinum(IV) bromide is the chemical compound composed of platinum and bromine with the formula PtBr4.

A solution of platinum(IV) bromide and gold(III) bromide in water can be used to test for the presence of caesium by putting a drop of the reagent and a drop of the unknown solution onto a piece of filter paper. A gray or black stain indicates a positive result; however, the mechanism for this reaction is unknown [2].

References

  1. ^ Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, FL: CRC Press, pp. 481, ISBN 0849305942, http://books.google.com/?id=lFjg0L-uOxoC&pg=PT866&dq=%22Platinum(IV)+bromide%22, retrieved 2008-06-19 
  2. ^ Wenger, P. E. (2007), Reagents for Qualitative Inorganic Analysis, Read Country Books, pp. 242, ISBN 1406748471, http://books.google.com/?id=SRAR3FOYxhEC&pg=PA360&dq=%22Platinum(IV)+bromide%22, retrieved 2008-06-18