A mineral is a naturally occurring solid chemical substance formed through biogeochemical processes, having characteristic chemical composition, highly ordered atomic structure, and specific physical properties. By comparison, a rock is an aggregate of minerals and/or mineraloids and does not have a specific chemical composition. Minerals range in composition from pure elements and simple salts to very complex silicates with thousands of known forms.[1] The study of minerals is called mineralogy.
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To be classified as a true mineral, a substance must be a solid and have a crystalline structure. It must also be a naturally occurring, homogeneous substance with a defined chemical composition.
The International Mineralogical Association approved the following definition in 1995:
According to this definition and classification scheme, biogenic materials were excluded from the mineral kingdom:
However, other researchers do not adhere to this exclusion rule. Lowenstam (1981), for example, states the following:[3]
The distinction is a matter of classification and less to do with the constituents of the minerals themselves. Skinner (2005) views all solids as potential minerals and includes biominerals in the mineral kingdom, which are those that are created by the metabolic activities of organisms. Inclusion of these biogenic minerals requires a expanded definition of a mineral as:
Mineral classification schemes and their definitions are evolving to match recent advances in mineral science. More recent classifications, for example, include an organic class – in both the new Dana and the Strunz classification schemes.[5][6] The organic class includes a very rare group of minerals with hydrocarbons. The IMA Commission on New Minerals and Mineral Names recently adopted (in 2009) a hierarchical scheme for the naming and classification of mineral groups and group names[7] and established seven commissions and four working groups to review and classify minerals into an official listing of their published names.[8] According to these new rules, "mineral species can be grouped in a number of different ways, on the basis of chemistry, crystal structure, occurrence, association, genetic history, or resource, for example, depending on the purpose to be served by the classification."[7]:1073
Recent advances in high-resolution genetic and x-ray absorption spectroscopy is opening new revelations on the biogeochemical relations between microrganisms and minerals that may make Nickel's (1995)[2] biogenic mineral exclusion obsolete and Skinner's (2005) biogenic mineral inclusion a necessity.[4] For example, the IMA commissioned 'Environmental Mineralogy and Geochemistry Working Group'[9] deals with minerals in the hydrosphere, atmosphere, and biosphere. Mineral forming microorganisms inhabit the areas that this working group deals with. These organisms exist on nearly every rock, soil, and particle surface spanning the globe reaching depths at 1600 meters below the sea floor (possibly further) and 70 kilometers into the stratosphere (possibly entering the mesosphere).[10][11][12] Biologists and geologists have recently started to research and appreciate the magnitude of mineral geoengineering that these creatures are capable of. Bacteria have contributed to the formation of minerals for billions of years and critically define the biogeochemical cycles on this planet. Microorganisms can precipitate metals from solution contributing to the formation of ore deposits in addition to their ability to catalyze mineral dissolution, to respire, precipitate, and form minerals.[13][14][15]
Prior to the International Mineralogical Association's listing, over 60 biominerals had been discovered, named, and published.[16] These minerals (a sub-set tabulated in Lowenstam (1981)[3]) are considered minerals proper according to the Skinner (2005) definition.[4] These biominerals are not listed in the International Mineral Association official list of mineral names,[17] however, many of these biomineral representatives are distributed amongst the 78 mineral classes listed in the `Dana' classification scheme.[4] Another rare class of minerals (primarily biological in origin) include the mineral liquid crystals that are crystalline and liquid at the same time. To date over 80,000 liquid crystaline compounds have been identified.[18][19]
Concerning the use of the term “mineral” to name this family of liquid crystals, one can argue that the term inorganic would be more appropriate. However, inorganic liquid crystals have long been used for organometallic liquid crystals. Therefore in order to avoid any confusion between these fairly chemically different families, and taking into account that a large number of these liquid crystals occur naturally in nature, we think that the use of the old fashioned but adequate “mineral” adjective taken sensus largo is more specific that an alternative such as “purely inorganic”, to name this subclass of the inorganic liquid crystals family.[19]
The Skinner (2005) definition[4] of a mineral takes this matter into account by stating that a mineral can be crystalline or amorphous. Liquid mineral crystals are amorphous. Biominerals and liquid mineral crystals, however, are not the primary form of minerals, most are geological in origin,[20] but these groups do help to identify at the margins of what constitutes a mineral proper.
A crystal structure is the orderly geometric spatial arrangement of atoms in the internal structure of a mineral. There are 14 basic crystal lattice arrangements of atoms in three dimensions, and these are referred to as the 14 "Bravais lattices". Each of these lattices can be classified into one of the seven crystal systems, and all crystal structures currently recognized fit in one Bravais lattice and one crystal system. This crystal structure is based on regular internal atomic or ionic arrangement that is often expressed in the geometric form that the crystal takes. Even when the mineral grains are too small to see or are irregularly shaped, the underlying crystal structure is always periodic and can be determined by X-ray diffraction. Chemistry and crystal structure together define a mineral. In fact, two or more minerals may have the same chemical composition, but differ in crystal structure (these are known as polymorphs). For example, pyrite and marcasite are both iron sulfide, but their arrangement of atoms differs. Similarly, some minerals have different chemical compositions, but the same crystal structure: for example, halite (made from sodium and chlorine), galena (made from lead and sulfur) and periclase (made from magnesium and oxygen) all share the same cubic crystal structure.
Crystal structure greatly influences a mineral's physical properties. For example, though diamond and graphite have the same composition (both are pure carbon), graphite is very soft, while diamond is the hardest of all known minerals. This happens because the carbon atoms in graphite are arranged into sheets which can slide easily past each other, while the carbon atoms in diamond form a strong, interlocking three-dimensional network.
There are currently more than 4,000 known minerals, according to the International Mineralogical Association (IMA), which is responsible for the approval of and naming of new mineral species found in nature. Of these, perhaps 100 can be called "common", 50 are "occasional", and the rest are "rare" to "extremely rare".
The chemical composition may vary between end members of a mineral system. For example the plagioclase feldspars comprise a continuous series from sodium and silicon-rich albite (NaAlSi3O8) to calcium and aluminium-rich anorthite (CaAl2Si2O8) with four recognized intermediate compositions between. Mineral-like substances that don't strictly meet the definition are sometimes classified as mineraloids.
Minerals with the same structure and forming solid solutions are named isomorphs, and form series; for example: forsterite and fayalite of the olivine series, ferberite and hubnerite of the wolframite series. Minerals with the same structure and not forming solid solutions are named isotypes, and form groups [classification of minerals (non silicates)]. Minerals with a similar structure are grouped in homeotype families: amphibole and pyroxene families [classification of minerals (silicates)].
Some ion groups with a similar radius can occupy the same structural site in the crystal cell:
More recent definitions:
A mineral is a naturally occurring solid with a definite chemical composition and a specific crystalline structure. A rock is an aggregate of one or more minerals. (A rock may also include organic remains and mineraloids.) Some rocks are predominantly composed of just one mineral. For example, limestone is a sedimentary rock composed almost entirely of the mineral calcite. Other rocks contain many minerals, and the specific minerals in a rock can vary widely. Some minerals, like quartz, mica or feldspar are common, while others have been found in only four or five locations worldwide. The vast majority of the rocks of the Earth's crust consist of quartz, feldspar, mica, chlorite, kaolin, calcite, epidote, olivine, augite, hornblende, magnetite, hematite, limonite and a few other minerals.[24] Over half of the mineral species known are so rare that they have only been found in a handful of samples, and many are known from only one or two small grains.
Commercially valuable minerals and rocks are referred to as industrial minerals. Rocks from which minerals are mined for economic purposes are referred to as ores (the rocks and minerals that remain, after the desired mineral has been separated from the ore, are referred to as tailings).
A main determining factor in the formation of minerals in a rock mass is the chemical composition of the mass, for a certain mineral can be formed only when the necessary elements are present in the rock. Calcite is most common in limestones, as these consist essentially of calcium carbonate; quartz is common in sandstones and in certain igneous rocks which contain a high percentage of silica.
Other factors are of equal importance in determining the natural association or paragenesis of rock-forming minerals, principally the mode of origin of the rock and the stages through which it has passed in attaining its present condition. Two rock masses may have very much the same bulk composition and yet consist of entirely different assemblages of minerals. The tendency is always for those compounds to be formed which are stable under the conditions under which the rock mass originated. A granite arises by the consolidation of a molten magma at high temperatures and great pressures and its component minerals are those stable under such conditions. Exposed to moisture, carbonic acid and other subaerial agents at the ordinary temperatures of the Earth's surface, some of these original minerals, such as quartz and white mica are relatively stable and remain unaffected; others weather or decay and are replaced by new combinations. The feldspar passes into kaolinite, muscovite and quartz, and any mafic minerals such as pyroxenes, amphiboles or biotite have been present they are often altered to chlorite, epidote, rutile and other substances. These changes are accompanied by disintegration, and the rock falls into a loose, incoherent, earthy mass which may be regarded as a sand or soil. The materials thus formed may be washed away and deposited as sandstone or siltstone. The structure of the original rock is now replaced by a new one; the mineralogical constitution is profoundly altered; but the bulk chemical composition may not be very different. The sedimentary rock may again undergo metamorphism. If penetrated by igneous rocks it may be recrystallized or, if subjected to enormous pressures with heat and movement during mountain building, it may be converted into a gneiss not very different in mineralogical composition though radically different in structure to the granite which was its original state.[24]
Classifying minerals can range from simple to very difficult. A mineral can be identified by several physical properties, some of them being sufficient for full identification without equivocation. In other cases, minerals can only be classified by more complex optical, chemical or X-ray diffraction analysis; these methods, however, can be costly and time-consuming.
Physical properties commonly used are:[1]
Minerals may be classified according to chemical composition. They are here categorized by anion group. The list below is in approximate order of their abundance in the Earth's crust. The list follows the Dana classification system[1][26] which closely parallels the Strunz classification.
The largest group of minerals by far are the silicates (most rocks are ≥95% silicates), which are composed largely of silicon and oxygen, with the addition of ions such as aluminium, magnesium, iron, and calcium. Some important rock-forming silicates include the feldspars, quartz, olivines, pyroxenes, amphiboles, garnets, and micas.
The carbonate minerals consist of those minerals containing the anion (CO3)2− and include calcite and aragonite (both calcium carbonate), dolomite (magnesium/calcium carbonate) and siderite (iron carbonate). Carbonates are commonly deposited in marine settings when the shells of dead planktonic life settle and accumulate on the sea floor. Carbonates are also found in evaporitic settings (e.g. the Great Salt Lake, Utah) and also in karst regions, where the dissolution and reprecipitation of carbonates leads to the formation of caves, stalactites and stalagmites. The carbonate class also includes the nitrate and borate minerals.
Sulfate minerals all contain the sulfate anion, SO42−. Sulfates commonly form in evaporitic settings where highly saline waters slowly evaporate, allowing the formation of both sulfates and halides at the water-sediment interface. Sulfates also occur in hydrothermal vein systems as gangue minerals along with sulfide ore minerals. Another occurrence is as secondary oxidation products of original sulfide minerals. Common sulfates include anhydrite (calcium sulfate), celestine (strontium sulfate), barite (barium sulfate), and gypsum (hydrated calcium sulfate). The sulfate class also includes the chromate, molybdate, selenate, sulfite, tellurate, and tungstate minerals.
The halide minerals are the group of minerals forming the natural salts and include fluorite (calcium fluoride), halite (sodium chloride), sylvite (potassium chloride), and sal ammoniac (ammonium chloride). Halides, like sulfates, are commonly found in evaporite settings such as salt lakes and landlocked seas such as the Dead Sea and Great Salt Lake. The halide class includes the fluoride, chloride, bromide and iodide minerals.
Oxide minerals are extremely important in mining as they form many of the ores from which valuable metals can be extracted. They also carry the best record of changes in the Earth's magnetic field. They commonly occur as precipitates close to the Earth's surface, oxidation products of other minerals in the near surface weathering zone, and as accessory minerals in igneous rocks of the crust and mantle. Common oxides include hematite (iron oxide), magnetite (iron oxide), chromite (iron chromium oxide), spinel (magnesium aluminium oxide – a common component of the mantle), ilmenite (iron titanium oxide), rutile (titanium dioxide), and ice (hydrogen oxide). The oxide class includes the oxide and the hydroxide minerals.
Many sulfide minerals are economically important as metal ores. Common sulfides include pyrite (iron sulfide – commonly known as fools' gold), chalcopyrite (copper iron sulfide), pentlandite (nickel iron sulfide), and galena (lead sulfide). The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, and the sulfosalts (sulfur and a second anion such as arsenic).
The phosphate mineral group actually includes any mineral with a tetrahedral unit AO4 where A can be phosphorus, antimony, arsenic or vanadium. By far the most common phosphate is apatite which is an important biological mineral found in teeth and bones of many animals. The phosphate class includes the phosphate, arsenate, vanadate, and antimonate minerals.
The elemental group includes native metals and intermetallic elements (gold, silver, copper), semi-metals and non-metals (antimony, bismuth, graphite, sulfur). This group also includes natural alloys, such as electrum (a natural alloy of gold and silver), phosphides, silicides, nitrides and carbides (which are usually only found naturally in a few rare meteorites).
The organic mineral class includes biogenic substances in which geological processes have been a part of the genesis or origin of the existing compound.[2] Minerals of the organic class include various oxalates, mellitates, citrates, cyanates, acetates, formates, hydrocarbons and other miscellaneous species.[5] Examples include whewellite, moolooite, mellite, fichtelite, carpathite, evenkite and abelsonite.
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