Lutetium(III) chloride

Lutetium(III) chloride
Identifiers
CAS number 10099-66-8
PubChem 24868595
ChemSpider 23297 Y
RTECS number OK8400000
Jmol-3D images Image 1
Properties
Molecular formula LuCl3
Molar mass 281.325 g/mol
Appearance colorless or white monoclinic crystals
Density 3.98 g/cm³
Melting point

905°C[1]

Boiling point

sublimes above 750°C[2]

Solubility in water soluble[3]
Structure
Crystal structure Monoclinic, mS16
Space group C2/m, No. 12
Hazards
R-phrases R36/37/38
S-phrases S26, S36[4]
Main hazards Xi (Irritant)
NFPA 704
0
2
1
Related compounds
Other anions Lutetium(III) oxide
Other cations Scandium(III) chloride
Yttrium(III) chloride
 Y (verify) (what is: Y/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Lutetium(III) chloride or lutetium trichloride is the chemical compound composed of lutetium and chlorine with the formula LuCl3. It forms hygroscopic white monoclinic crystals[1]. Lutetium(III) chloride has the YCl3 (AlCl3) layer structure with octahedral lutetium ions.[5]

Reactions

Pure lutetium metal can be produced from lutetium(III) chloride by heating it together with elemental calcium: [6]

2LuCl3 + 3Ca → 2Lu + 3CaCl2

References

  1. ^ a b Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, FL: CRC Press, pp. 472, ISBN 0849305942, http://books.google.com/?id=lFjg0L-uOxoC&pg=PT857, retrieved 2008-06-27 
  2. ^ "Chemistry: Periodic Table: Lutetium: compound data (lutetium (III) chloride)". WebElements. http://202.114.88.54/g/web18/wangluo/webelements/webelements/compounds/text/lu/cl3lu1-10099668.html. Retrieved 2008-06-27. 
  3. ^ Perry, Dale L.; Phillips, Sidney L. (1995), Handbook of Inorganic Compounds, CRC Press, pp. 232, ISBN 0849386713, http://books.google.com/?id=0fT4wfhF1AsC&pg=PA232, retrieved 2008-06-27 
  4. ^ "450960 Lutetium(III) chloride anhydrous, powder, 99.99% trace metals basis". Sigma-Aldrich. http://www.sigmaaldrich.com/catalog/search/ProductDetail/ALDRICH/450960. Retrieved 2008-06-27. 
  5. ^ Wells A.F. (1984) Structural Inorganic Chemistry 5th edition Oxford Science Publications ISBN 0-19-855370-6
  6. ^ Patnaik, Pradyot (2004), Handbook of Inorganic Chemicals, Amsterdam: McGraw-Hill Professional, pp. 244, ISBN 0070494398, http://books.google.com/?id=Xqj-TTzkvTEC&pg=PA510&dq=%22Lutetium+chloride%22, retrieved 2008-06-27