Kingdon trap

A Kingdon trap is a type of ion trap.

In the Kingdon trap there is no potential minimum to store the ions; however, they are stored with a finite angular momentum about the central wire and the applied electric field in the device allows for the stability of the ion trajectories.[1] It consists of a thin central wire, an outer cylindrical electrode and isolated end cap electrodes at both ends. A static applied voltage results in a radial logarithmic potential between the electrodes. In 1981, Knight introduced a modified outer electrode that included an axial quadrupole term that confines the ions on the trap axis.[2] The dynamic Kingdon Trap has an additional AC voltage that uses strong defocusing to permanently store charged particles.[3] The dynamic Kingdon Trap does not require the trapped ions to have angular momentum with respect to the filament. An Orbitrap is a modified Kingdon trap has been used for mass spectrometry. Though the idea has been suggested and computer simulations performed[4] neither the Kingdon nor the Knight configurations were reported to produce mass spectra, as the simulations indicated mass resolving power would be problematic.

References

  1. ^ Major, Fouad G (2005). Charged particle traps: physics and techniques of charged particle field. Springer. ISBN 3540220437. 
  2. ^ Knight, R. D. (1981). "Storage of ions from laser-produced plasmas". Applied Physics Letters 38 (4): 221–223. Bibcode 1981ApPhL..38..221K. doi:10.1063/1.92315. 
  3. ^ Blümel, R (1995). "Dynamic Kingdon trap". Physical Review A 51 (1): R30–R33. Bibcode 1995PhRvA..51...30B. doi:10.1103/PhysRevA.51.R30. PMID 9911663. 
  4. ^ Oksman, Pentti (1995-01-10). "A Fourier transform time-of-flight mass spectrometer. A SIMION calculation approach". International Journal of Mass Spectrometry and Ion Processes 141 (1): 67–76. Bibcode 1995IJMSI.141...67O. doi:10.1016/0168-1176(94)04086-M.