Isotopes of beryllium

Although beryllium (Be) has 12 known isotopes, only one of these isotopes (9
Be
) is stable and a primordial nuclide. As such, it is considered a monoisotopic element. It is also a mononuclidic element, because its other isotopes have such short half-lives that none are primordial and their abundance is very low. Most 9
Be
in the universe is thought to be formed by cosmic ray nucleosynthesis from cosmic ray spallation in the period between the Big Bang and the formation of the solar system.

Of the 11 radioisotopes of beryllium, the most stable are 10Be with a half-life of 1.39 million years and 7Be with a half-life of 53.22 days. All other radioisotopes have half-lives under 13.85 seconds, most under 20 milliseconds. The least stable isotope is 6Be, with a half-life measured as 5.03 zeptoseconds.

Beryllium is unique as being the only monoisotopic element with both an even number of protons and an odd number of neutrons. There are 20 other monoisotopic elements (fluorine, sodium, aluminum, phosphorus, scandium, manganese, cobalt, arsenic, yttrium, niobium, rhodium, iodine, cesium, praseodymium, terbium, holmium, thulium, gold, bismuth, and thorium) but all have odd atomic numbers (except thorium), and even numbers of neutrons.

The natural light-element ratio of equal protons and neutron numbers is prevented in beryllium by the extreme instability of 8
Be
toward double-alpha decay, which is favored due to the extremely tight binding of 4
He
nuclei. The half-life for the decay of 8
Be
is only 6.7(17)×10−17 seconds.

Beryllium is prevented from having a stable isotope with 4 protons and 6 neutrons by the very large mismatch in proton/neutron ratio for such a light element. Nevertheless, this isotope, 10
Be
, has a half-life of 1.39 million years, which indicates unusual stability for a light isotope with such a large neutron/proton imbalance.

Still other possible beryllium isotopes have even more severe mismatches in neutron and proton number, and thus are even less stable.

The isotopes 7
Be
, with a half-life of 53 days, and 10
Be
are both cosmogenic nuclides because they are made on a recent timescale in the solar system by cosmic ray spallations, like 14
C
. These two radioisotopes of beryllium in the atmosphere track the sun spot cycle and solar activity, since this affects the magnetic field that shields the Earth from cosmic rays. The rate at which the short-lived 7
Be
is transferred from the air to the ground is controlled in part by the weather.

7
Be
decay in the sun is one of the sources of solar neutrinos, and the first type ever detected using the Homestake experiment.

Beryllium has a standard atomic mass of: 9.012182(3) u

Contents

Table

nuclide
symbol
Z(p) N(n)  
isotopic mass (u)
 
half-life decay
mode(s)[1][n 1]
daughter
isotope(s)[n 2]
nuclear
spin
representative
isotopic
composition
(mole fraction)
range of natural
variation
(mole fraction)
5
Be
4 1 5.04079(429)# p 4
Li
(1/2+)#
6
Be
4 2 6.019726(6) 5.0(3)×10−21 s
[0.092(6) MeV]
2p 4
He
0+
7
Be
[n 3]
4 3 7.01692983(11) 53.22(6) d EC 7
Li
3/2- Trace[n 4]
8
Be
[n 5]
4 4 8.00530510(4) 6.7(17)×10−17 s
[6.8(17) eV]
fission 2 4
He
0+
9
Be
4 5 9.0121822(4) Stable 3/2- 1.0000
10
Be
4 6 10.0135338(4) 1.39×106 a β 10
B
0+ Trace[n 4]
11
Be
[n 6]
4 7 11.021658(7) 13.81(8) s β (97.1%) 11
B
1/2+
β, α (2.9%) 7
Li
12
Be
4 8 12.026921(16) 21.49(3) ms β (99.48%) 12
B
0+
β, n (0.52%) 11
B
13
Be
4 9 13.03569(8) .5(1) ns n 12
Be
1/2+
14
Be
[n 7]
4 10 14.04289(14) 4.84(10) ms β, n (81.0%) 13
B
0+
β (14.0%) 14
B
β, 2n (5.0%) 12
B
15
Be
4 11 15.05346(54)# <200 ns
16
Be
4 12 16.06192(54)# <200 ns 0+
  1. ^ Abbreviations:
    EC: Electron capture
  2. ^ Bold for stable isotopes
  3. ^ Produced in Big Bang nucleosynthesis, but not primordial, as it all quickly decayed to 7Li
  4. ^ a b cosmogenic nuclide
  5. ^ Intermediate product of triple alpha process in stellar nucleosynthesis as part of the path producing 12C
  6. ^ Has 1 halo neutron
  7. ^ Has 4 halo neutrons

Notes

See also


References

  1. ^ http://www.nucleonica.net/unc.aspx
Isotopes of lithium Isotopes of beryllium Isotopes of boron
Index to isotope pages · Table of nuclides