Imidogen | |
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Imidogene |
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λ1-Azanylidene |
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Other names
Aminylene Azanylene |
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Identifiers | |
CAS number | 13774-92-0 |
PubChem | 5460607 |
ChemSpider | 4574105 |
ChEBI | CHEBI:29339 |
Gmelin Reference | 66 |
Jmol-3D images | Image 1 |
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Properties | |
Molecular formula | HN |
Molar mass | 15.01 g mol−1 |
Exact mass | 15.010899037 g mol-1 |
Structure | |
Molecular shape | linear |
Thermochemistry | |
Std enthalpy of formation ΔfH |
358.43 kJ mol-1 |
Standard molar entropy S |
181.22 kJ K-1 mol-1 |
Specific heat capacity, C | 21.19 J K-1 mol-1 |
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Infobox references |
The Imidogene radical, HN:, is the neutral form of the imide ion (HN2−). Imidogene radicals are highly reactive and consequently short lived; however, they form an important part of radical chemistry. It is an interesting radical which reacts differently depending on its spin multiplicity, it has a triplet ground state. In sufficiently high concentration, imidogen polymerises to form triazidine that without stablising substituents is in itself only a metastable molecule.