Hypoiodous acid

Hypoiodous acid
Identifiers
CAS number ? Y
PubChem 123340
ChemSpider 109942 Y
ChEBI CHEBI:29231 Y
Jmol-3D images Image 1
Properties
Molecular formula HIO
Molar mass 143.89 g/mol
Appearance  ?
Density  ?
Melting point

?

Boiling point

?

Solubility in water  ?
 Y (verify) (what is: Y/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Hypoiodous acid (HIO) is formed when mercury(II) oxide is shaken with aqueous iodine.[1] It rapidly decomposes by disproportionation:[1]

5HIO → HIO3 + 2I2 + 2H2O

Reactive solutions of hypoiodites (salts of hypoiodous acid) can be prepared by reacting I2 with alkali hydroxides.[1]. They rapidly disproportionate to form iodides and iodates.[1]

In theory, HIO should be a powerful disinfectant as it is the iodine analogue to the hypochlorous acid formed when mixing chlorine with water. HIO is likely the active ingredient responsible for disinfection by iodine solutions used in the medical profession such as betadine or povidone iodine.

References

  1. ^ a b c d Egon Wiberg, Arnold Frederick Holleman (2001) Inorganic Chemistry, Elsevier ISBN 0-12-352651-5