A hemicellulose is any of several heteropolymers (matrix polysaccharides), such as arabinoxylans, present along with cellulose in almost all plant cell walls. While cellulose is crystalline, strong, and resistant to hydrolysis, hemicellulose has a random, amorphous structure with little strength. It is easily hydrolyzed by dilute acid or base as well as myriad hemicellulase enzymes.
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Hemicelluloses include xylan, glucuronoxylan, arabinoxylan, glucomannan, and xyloglucan.
These polysaccharides contain many different sugar monomers. In contrast, cellulose contains only anhydrous glucose. For instance, besides glucose, sugar monomers in hemicellulose can include xylose, mannose, galactose, rhamnose, and arabinose. Hemicelluloses contain most of the D-pentose sugars, and occasionally small amounts of L-sugars as well. Xylose is always the sugar monomer present in the largest amount, but mannuronic acid and galacturonic acid also tend to be present.
Unlike cellulose, hemicellulose (also a polysaccharide) consists of shorter chains - 500-3,000 sugar units as opposed to 7,000 - 15,000 glucose molecules per polymer seen in cellulose. In addition, hemicellulose is a branched polymer, while cellulose is unbranched.
Hemicelluloses are embedded in the cell walls of plants, sometimes in chains that form a 'ground' - they bind with pectin to cellulose to form a network of cross-linked fibres.
Hemicelluloses are synthesised from sugar nucleotides in the Golgi. Two models explain their synthesis: 1) a ‘2 component model' where modification occurs at two transmembrane proteins, and 2) a '1 component model' where modification occurs only at one transmembrane protein. After synthesis, hemicelluloses are transported to the plasma membrane via golgi vesicles.
As percent content of hemicellulose increases in animal feed, the voluntary feed intake decreases.
Hemicellulose is represented by the difference between neutral detergent fiber (NDF) and acid detergent fiber (ADF).
Microfibrils are cross-linked together by hemicellulose homopolymers. Lignins assist and strengthen the attachment of hemicelluloses to microfibrils.