Fluoromethane

Fluoromethane
Identifiers
Abbreviations R41
CAS number 593-53-3 Y, 558-21-4 (2H3Y, 20666-44-8 (13CY
PubChem 11638 (2H3Y, 450707 (11CY, 12336970 (13CY, 9833918 (17F), 450725 (18FY, 11638 Y
ChemSpider 11148 (2H3) Y, 396977 (11CY, 21170290 (13CY, 8009639 (17FY, 396995 (18FY, 11148 Y
EC number 209-796-6
UN number UN 2454
KEGG C11147 Y
MeSH Fluoromethane
ChEBI CHEBI:28826 Y
ChEMBL CHEMBL116838 Y
Beilstein Reference 1730725
Gmelin Reference 391
Jmol-3D images Image 1
Properties
Molecular formula CH3F
Molar mass 34.03 g/mol
Appearance Colorless, odorless gas
Density 1.4397 g/L

0.557 g/cm3 (liquid) at saturation pressure at 25 °C

Melting point

131.4 K (-141.8 °C)

Boiling point

195.0 K (-78.2 °C)

Solubility in water 1.66 l/kg (2.295 g/l)
Vapor pressure 3.3 MPa
Hazards
EU classification Very flammable (F+)
R-phrases R12
S-phrases S9, S16, S23, S24/25, S26, S28, S33, S36/37/39, S60
NFPA 704
4
1
0
 Y (verify) (what is: Y/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Fluoromethane, also known as methyl fluoride, Freon 41, Halocarbon-41 and HFC-41, is a non-toxic, liquefiable, and flammable gas at standard temperature and pressure. It is made of carbon, hydrogen, and fluorine. The name stems from the fact that it is methane (CH4) plus fluorine, minus a hydrogen. It is used in the manufacture of semiconductor and electronic products. In the presence of an RF field fluoromethane will dissociate into fluoride ions that selectively etch silicon compound films (reactive-ion etching).

Bond energy of C-F is 552 kJ/mol and its length is 0.139 nm (typically 0.14 nm). Its molecular geometry is tetrahedral.

Its specific heat capacity is Cp = 38.171 J.mol-1.K-1 at 25 °C. Critical point of fluoromethane is at 44.9 °C (318.1 K) and 6.280 MPa.

External links