Divinylbenzene

Divinylbenzene
Identifiers
CAS number 1321-74-0
EC number 215-325-5
Properties
Molecular formula C10H10
Molar mass 130.19 g mol−1
Melting point

-66.9 to -52°C

Boiling point

195°C

Solubility in water Insoluble
Solubility in other solvents Insoluble in water
Soluble in ethanol and ether
Hazards
Flash point 76°C
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Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Divinylbenzene (DVB) consists of a benzene ring bonded to two vinyl groups. It is related to styrene (vinylbenzene) by the addition of a second vinyl group.[1] Divinylbenzene, as it is usually encountered, is a 2:1 mixture of m- and p-divinylbenzene, containing also the corresponding ethylvinylbenzene isomers. It is manufactured by the thermal dehydrogenation of isomeric diethylbenzenes. Under synthesis conditions, o-divinylbenzene converts to naphthalene and thus is not a component of the usual mixtures of DVB.[2]

Applications

When reacted together with styrene, divinylbenzene can be used as a reactive monomer in polyester resins. Styrene and divinylbenzene react together to form the copolymer styrene-divinylbenzene, S-DVB or Sty-DVB. The resulting cross-linked polymer is mainly used for the production of ion exchange resin.[2]

Density is 0.914 g/mL

Nomenclature

See also: Arene substitution patterns Divinylbenzene can exist in the form of 3 structural isomers that differ with respect to the positioning of the vinyl groups.

These compounds are systematically called as diethenylbenzene, although this nomenclature is rarely encountered.

References

  1. ^ CRC Handbook of Chemistry and Physics 65Th Ed.
  2. ^ a b Denis H. James William M. Castor, “Styrene” in Ullmann’s Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005.