Chaoite or white carbon is a mineral described as an allotrope of carbon whose existence is disputed. It was discovered in shock-fused graphite gneiss from the Ries crater in Bavaria. It has been described as slightly harder than graphite, with a reflection colour of grey to white. [1] From its electron diffraction pattern, the mineral has been considered to have a carbyne structure,[2] the linear acetylenic carbon allotrope of carbon. A later report has called this identification, and the very existence of carbyne phases, into question, arguing that the new reflections in the diffraction pattern are due to clay impurities. [3]
It has been claimed that an identical form can be prepared from graphite by sublimation at 2700-3000 K or by irradiating it with a laser in high vacuum. This substance has been termed ceraphite. [4]
A review [5] cautions that "in spite of these seemingly definitive reports … several other groups have tried unsuccessfully to reproduce these experiments. Independent confirmatory work is obviously needed … and at the present time white graphite appears to be the carbon analog of polywater". In other words, unlikely—even fantastic—claims were made that were not supported by the available data.
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