Aldose

An aldose is a monosaccharide (a simple sugar) that contains only one aldehyde (-CH=O) group per molecule. The chemical formula takes the form Cn(H2O)n. The simplest possible aldose is the diose glycolaldehyde, which only contains two carbon atoms.[1]

Because they have at least one asymmetric carbon centre, aldoses exhibit stereoisomerism. This means an aldose can exist in either a D form or L form of a Fischer projection. Biological systems tend to recognise D-aldoses more than L-aldoses.

An aldose differs from a ketose in that it has a carbonyl group at the end of the carbon chain instead of in the middle. This allows ketoses and aldoses to be chemically differentiated through Seliwanoff's test.[2] An aldose may isomerize to a ketose through the Lobry-de Bruyn-van Ekenstein transformation.[3]

List of aldoses

References

  1. ^ Berg, J.M. (2006). Biochemistry (6th ed.). New York: W.H. Freeman and Company. 
  2. ^ "Seliwanoff's Test". Harper College. http://www.harpercollege.edu/tm-ps/chm/100/dgodambe/thedisk/carbo/seli/seli.htm. Retrieved 2011-07-10. 
  3. ^ "Lobry de Bruyn-van Ekenstein Transformation". Drug Future. http://www.drugfuture.com/organicnamereactions/ONR237.htm. Retrieved 2011-07-10. 

See also