Radioactive wastes are waste types containing radioactive chemical elements that do not have a practical purpose. They are usually the products of nuclear processes, such as nuclear fission. However, industries not directly connected to the nuclear industry may produce large quantities of radioactive waste. The majority of radioactive waste is "low-level waste", meaning it contains low levels of radioactivity per mass or volume. This type of waste often consists of used protective clothing, which is only slightly contaminated but still dangerous in case of radioactive contamination of a human body through ingestion, inhalation, absorption, or injection.
The issue of disposal methods for nuclear waste was one of the most pressing current problems the international nuclear industry faced when trying to establish a long term energy production plan, yet there was hope it could be safely solved. A recent research report on the Nuclear Industry perspective of the current state of scientific knowledge in predicting the extent that waste would find its way from the deep burial facility - back to soil and drinking water (such that it presents a direct threat to the health of human beings - as well as to other forms of life) is presented in a document from the IAEA (The International Atomic Energy Agency) - published in October 2007. This document states "The capacity to model all the effects involved in the dissolution of the waste form, in conditions similar to the disposal site, is the final goal of all the research undertaken by many research groups over many years. As we will see in this report, this kind of investigation is far from being finished."[1] In the United States, DOE acknowledges progress in addressing the waste problems of the industry, and successful remediation of some contaminated sites, yet also major uncertainties and sometimes complications and setbacks in handling the issue properly, cost effectively, and in the projected time frame.[2] In other countries with lower ability or will to maintain environmental integrity the issue would be even more problematic.
In the United States alone, the Department of Energy states there are "millions of gallons of radioactive waste" as well as "thousands of tons of spent nuclear fuel and material" and also "huge quantities of contaminated soil and water."[2] Despite copious quantities of waste, the DOE has stated a goal of cleaning all presently contaminated sites successfully by 2025.[2] The Fernald, Ohio site for example had "31 million pounds of uranium product", "2.5 billion pounds of waste", "2.75 million cubic yards of contaminated soil and debris", and a "223 acre portion of the underlying Great Miami Aquifer had uranium levels above drinking standards."[2] The United States has at least 108 sites designated as areas that are contaminated and unusable, sometimes many thousands of acres.[3][2] DOE wishes to clean or mitigate many or all by 2025, however the task can be difficult and it acknowledges that some will never be completely remediated. In just one of these 108 larger designations, Oak Ridge National Laboratory, there were for example at least "167 known contaminant release sites" in one of the three subdivisions of the 37,000-acre (150 km2) site.[2] Some of the U.S. sites were smaller in nature, however, cleanup issues were simpler to address, and DOE has successfully completed cleanup, or at least closure, of several sites.[2]
Radioactive waste typically comprises a number of radioisotopes: unstable configurations of elements that decay, emitting ionizing radiation which can be harmful to human health and to the environment. Those isotopes emit different types and levels of radiation, which last for different periods of time..
Prop: Unit: |
t½ a |
Yield % |
Q * KeV |
βγ * |
---|---|---|---|---|
155Eu | 4.76 | .0803 | 252 | βγ |
85Kr | 10.76 | .2180 | 687 | βγ |
113mCd | 14.1 | .0008 | 316 | β |
90Sr | 28.9 | 4.505 | 2826 | β |
137Cs | 30.23 | 6.337 | 1176 | βγ |
121mSn | 43.9 | .00005 | 390 | βγ |
151Sm | 90 | .5314 | 77 | β |
Prop: Unit: |
t½ Ma |
Yield % |
Q * KeV |
βγ * |
---|---|---|---|---|
99Tc | .211 | 6.1385 | 294 | β |
126Sn | .230 | .1084 | 4050 | βγ |
79Se | .295 | .0447 | 151 | β |
93Zr | 1.53 | 5.4575 | 91 | βγ |
135Cs | 2.3 | 6.9110 | 269 | β |
107Pd | 6.5 | 1.2499 | 33 | β |
129I | 15.7 | .8410 | 194 | βγ |
The radioactivity of all nuclear waste diminishes with time. All radioisotopes contained in the waste have a half-life - the time it takes for any radionuclide to lose half of its radioactivity and eventually all radioactive waste decays into non-radioactive elements. Certain radioactive elements (such as plutonium-239) in “spent” fuel will remain hazardous to humans and other living beings for hundreds of thousands of years. Other radioisotopes will remain hazardous for millions of years. Thus, these wastes must be shielded for centuries and isolated from the living environment for hundreds of millennia.[4] Some elements, such as Iodine-131, have a short half-life (around 8 days in this case) and thus they will cease to be a problem much more quickly than other, longer-lived, decay products but their activity is much greater initially. The two tables show some of the major radioisotopes, their half-lives, and their radiation yield as a proportion of the yield of fission of Uranium-235.
The faster a radioisotope decays, the more radioactive it will be. The energy and the type of the ionizing radiation emitted by a pure radioactive substance are important factors in deciding how dangerous it will be. The chemical properties of the radioactive element will determine how mobile the substance is and how likely it is to spread into the environment and contaminate human bodies. This is further complicated by the fact that many radioisotopes do not decay immediately to a stable state but rather to a radioactive decay product leading to decay chains.
The chemical properties of the radioactive substance and the other substances found within (and near) the waste store has a great effect upon the ability of the waste to cause harm to humans or other organisms. For instance TcO4- tends to adsorb on the surfaces of steel objects which reduces its ability to move out of the waste store in water.
Exposure to high levels of radioactive waste may cause serious harm or death. Treatment of an adult animal with radiation or some other mutation-causing effect, such as a cytotoxic anti-cancer drug, may cause cancer in the animal. In humans it has been calculated that a 1 sievert dose has a 5% chance of causing cancer and a 1% chance of causing a mutation in a gamete which can be passed to the next generation. If a developing organism such as an unborn child is irradiated, then it is possible to induce a birth defect but it is unlikely that this defect will be in a gamete or a gamete forming cell.
Depending on the decay mode and the pharmacokinetics of an element (how the body processes it and how quickly), the threat due to exposure to a given activity of a radioisotope will differ. For instance Iodine-131 is a short-lived beta and gamma emitter but because it concentrates in the thyroid gland, it is more able to cause injury than cesium-137 which, being water soluble, is rapidly excreted in urine. In a similar way, the alpha emitting actinides and radium are considered very harmful as they tend to have long biological half-lives and their radiation has a high linear energy transfer value. Because of such differences, the rules determining biological injury differ widely according to the radioisotope, and sometimes also the nature of the chemical compound which contains the radioisotope.
The main objective in managing and disposing of radioactive (or other) waste is to protect people and the environment. This means isolating or diluting the waste so that the rate or concentration of any radionuclide returned to the biosphere is harmless. To achieve this the preferred technology to date has been deep and secure burial for the more dangerous wastes; transmutation, long-term retrievable storage, and removal to space have also been suggested. Management options for waste are discussed below.
Radioactivity by definition reduces over time, so in principle the waste needs to be isolated for a particular period of time until its components have decayed such that it no longer poses a threat. In practice this can mean periods of hundreds of thousands of years, depending on the nature of the waste involved.
Though an affirmative answer is often taken for granted, the question as to whether or not we should endeavor to avoid causing harm to remote future generations, perhaps thousands upon thousands of years hence, is essentially one which must be dealt with by philosophy.
Radioactive waste comes from a number of sources. The majority originates from the nuclear fuel cycle and nuclear weapon reprocessing. However, other sources include medical and industrial wastes, as well as naturally occurring radioactive materials (NORM) that can be concentrated as a result of the processing or consumption of coal, oil and gas, and some minerals.
Waste from the front end of the nuclear fuel cycle is usually alpha emitting waste from the extraction of uranium. It often contains radium and its decay products.
Uranium dioxide (UO2) concentrate from mining is not very radioactive - only a thousand or so times as radioactive as the granite used in buildings. It is refined from yellowcake (U3O8), then converted to uranium hexafluoride gas (UF6). As a gas, it undergoes enrichment to increase the U-235 content from 0.7% to about 4.4% (LEU). It is then turned into a hard ceramic oxide (UO2) for assembly as reactor fuel elements.
The main by-product of enrichment is depleted uranium (DU), principally the U-238 isotope, with a U-235 content of ~0.3%. It is stored, either as UF6 or as U3O8. Some is used in applications where its extremely high density makes it valuable, such as the keels of yachts, and anti-tank shells.[5] It is also used (with recycled plutonium) for making mixed oxide fuel (MOX) and to dilute highly enriched uranium from weapons stockpiles which is now being redirected to become reactor fuel. This dilution, also called downblending, means that any nation or group that acquired the finished fuel would have to repeat the (very expensive and complex) enrichment process before assembling a weapon.
The back end of the nuclear fuel cycle, mostly spent fuel rods, contains fission products that emit beta and gamma radiation, and actinides that emit alpha particles, such as uranium-234, neptunium-237, plutonium-238 and americium-241, and even sometimes some neutron emitters such as californium (Cf). These isotopes are formed in nuclear reactors.
It is important to distinguish the processing of uranium to make fuel from the reprocessing of used fuel. Used fuel contains the highly radioactive products of fission (see high level waste below). Many of these are neutron absorbers, called neutron poisons in this context. These eventually build up to a level where they absorb so many neutrons that the chain reaction stops, even with the control rods completely removed. At that point the fuel has to be replaced in the reactor with fresh fuel, even though there is still a substantial quantity of uranium-235 and plutonium present. In the United States, this used fuel is stored, while in countries such as the United Kingdom, France, and Japan, the fuel is reprocessed to remove the fission products, and the fuel can then be re-used. This reprocessing involves handling highly radioactive materials, and the fission products removed from the fuel are a concentrated form of high-level waste as are the chemicals used in the process.
When dealing with uranium and plutonium, the possibility that they may be used to build nuclear weapons is often a concern. Active nuclear reactors and nuclear weapons stockpiles are very carefully safeguarded and controlled. However, high-level waste from nuclear reactors may contain plutonium. Ordinarily, this plutonium is reactor-grade plutonium, containing a mixture of plutonium-239 (highly suitable for building nuclear weapons), plutonium-240 (an undesirable contaminant and highly radioactive), plutonium-241, and plutonium-238; these isotopes are difficult to separate. Moreover, high-level waste is full of highly radioactive fission products. However, most fission products are relatively short-lived. This is a concern since if the waste is stored, perhaps in deep geological storage, over many years the fission products decay, decreasing the radioactivity of the waste and making the plutonium easier to access. Moreover, the undesirable contaminant Pu-240 decays faster than the Pu-239, and thus the quality of the bomb material increases with time (although its quantity decreases during that time as well). Thus, some have argued, as time passes, these deep storage areas have the potential to become "plutonium mines", from which material for nuclear weapons can be acquired with relatively little difficulty. Critics of the latter idea point out that the half-life of Pu-240 is 6,560 years and Pu-239 is 24,110 years, and thus the relative enrichment of one isotope to the other with time occurs with a half-life of 9,000 years (that is, it takes 9000 years for the fraction of Pu-240 in a sample of mixed plutonium isotopes, to spontaneously decrease by half-- a typical enrichment needed to turn reactor-grade into weapons-grade Pu). Thus "weapons grade plutonium mines" would be a problem for the very far future (>9,000 years from now), so that there remains a great deal of time for technology to advance to solve this problem, before it becomes acute.
Pu-239 decays to U-235 which is suitable for weapons and which has a very long half life (roughly 109 years). Thus plutonium may decay and leave uranium-235. However, modern reactors are only moderately enriched with U-235 relative to U-238, so the U-238 continues to serve as denaturation agent for any U-235 produced by plutonium decay.
One solution to this problem is to recycle the plutonium and use it as a fuel e.g. in fast reactors. But in the minds of some, the very existence of the nuclear fuel reprocessing plant needed to separate the plutonium from the other elements represents a proliferation concern. In pyrometallurgical fast reactors, the waste generated is an actinide compound that cannot be used for nuclear weapons.
Waste from nuclear weapons reprocessing (as opposed to production, which requires primary processing from reactor fuel) is unlikely to contain much beta or gamma activity other than tritium and americium. It is more likely to contain alpha emitting actinides such as Pu-239 which is a fissile material used in bombs, plus some material with much higher specific activities, such as Pu-238 or Po.
In the past the neutron trigger for a bomb tended to be beryllium and a high activity alpha emitter such as polonium; an alternative to polonium is Pu-238. For reasons of national security, details of the design of modern bombs are normally not released to the open literature. It is likely however that a D-T fusion reaction in either an electrically driven device or a D-T fusion reaction driven by the chemical explosives would be used to start up a modern device.
Some designs might well contain a radioisotope thermoelectric generator using Pu-238 to provide a longlasting source of electrical power for the electronics in the device.
It is likely that the fissile material of an old bomb which is due for refitting will contain decay products of the plutonium isotopes used in it, these are likely to include U-236 from Pu-240 impurities, plus some U-235 from decay of the Pu-239; however, due to the relatively long half-life of these Pu isotopes, these wastes from radioactive decay of bomb core material would be very small, and in any case, far less dangerous (even in terms of simple radioactivity) than the Pu-239 itself.
The beta decay of Pu-241 forms Am-241; the in-growth of americium is likely to be a greater problem than the decay of Pu-239 and Pu-240 as the americium is a gamma emitter (increasing external-exposure to workers) and is an alpha emitter which can cause the generation of heat. The plutonium could be separated from the americium by several different processes; these would include pyrochemical processes and aqueous/organic solvent extraction. A truncated PUREX type extraction process would be one possible method of making the separation.
Radioactive medical waste tends to contain beta particle and gamma ray emitters. It can be divided into two main classes. In diagnostic nuclear medicine a number of short-lived gamma emitters such as technetium-99m are used. Many of these can be disposed of by leaving it to decay for a short time before disposal as normal trash. Other isotopes used in medicine, with half-lives in parentheses:
Industrial source waste can contain alpha, beta, neutron or gamma emitters. Gamma emitters are used in radiography while neutron emitting sources are used in a range of applications, such as oil well logging.[1]
Processing of substances containing natural radioactivity; this is often known as NORM. A lot of this waste is alpha particle-emitting matter from the decay chains of uranium and thorium. The main source of radiation in the human body is potassium-40 (40K). There is a natural background radioactivity that life systems are built to resist. Most rocks, due to their components, have a certain, but low level, of radioactivity.
Coal contains a small amount of radioactive uranium, barium, thorium and potassium, but, in the case of pure coal, this is significantly less than the average concentration of those elements in the Earth's crust. However, the surrounding strata, if shale or mudstone, often contains slightly more than average and this may also be reflected in the ash content of 'dirty' coals [6][7]. The more active ash minerals become concentrated in the fly ash precisely because they do not burn well [7]. However, the radioactivity of fly ash is still very low. It is about the same as black shale and is less than phosphate rocks, but is more of a concern because a small amount of the fly ash ends up in the atmosphere where it can be inhaled.[8]
Residues from the oil and gas industry often contain radium and its daughters. The sulphate scale from an oil well can be very radium rich, while the water, oil and gas from a well often contains radon. The radon decays to form solid radioisotopes which form coatings on the inside of pipework. In an oil processing plant the area of the plant where propane is processed is often one of the more contaminated areas of the plant as radon has a similar boiling point as propane.[9]
Although not significantly radioactive, uranium mill tailings are waste. They are byproduct material from the rough processing of uranium-bearing ore. They are sometimes referred to as 11(e)2 wastes, from the section of the U.S. Atomic Energy Act that defines them. Uranium mill tailings typically also contain chemically-hazardous heavy metals such as lead and arsenic. Vast mounds of uranium mill tailings are left at many old mining sites, especially in Colorado, New Mexico, and Utah.
Low level waste (LLW) is generated from hospitals and industry, as well as the nuclear fuel cycle. It comprises paper, rags, tools, clothing, filters, etc., which contain small amounts of mostly short-lived radioactivity. Commonly, LLW is designated as such as a precautionary measure if it originated from any region of an 'Active Area', which frequently includes offices with only a remote possibility of being contaminated with radioactive materials. Such LLW typically exhibits no higher radioactivity than one would expect from the same material disposed of in a non-active area, such as a normal office block. Some high activity LLW requires shielding during handling and transport but most LLW is suitable for shallow land burial. To reduce its volume, it is often compacted or incinerated before disposal. Low level waste is divided into four classes, class A, B, C and GTCC, which means "Greater Than Class C".
Intermediate level waste (ILW) contains higher amounts of radioactivity and in some cases requires shielding. ILW includes resins, chemical sludge and metal reactor fuel cladding, as well as contaminated materials from reactor decommissioning. It may be solidified in concrete or bitumen for disposal. As a general rule, short-lived waste (mainly non-fuel materials from reactors) is buried in shallow repositories, while long-lived waste (from fuel and fuel-reprocessing) is deposited in deep underground facilities. U.S. regulations do not define this category of waste; the term is used in Europe and elsewhere.
High level waste (HLW) is produced by nuclear reactors. It contains fission products and transuranic elements generated in the reactor core. It is highly radioactive and often thermally hot. LLW and ILW accounts for over 95% of the total radioactivity produced in the process of nuclear electricity generation. The amount of HLW worldwide is currently increasing by about 12,000 metric tons every year, which is the equivalent to about 100 double-decker busses or a two-story structure built on top of a basketball court.[10]
Transuranic waste (TRUW) as defined by U.S. regulations is, without regard to form or origin, waste that is contaminated with alpha-emitting transuranic radionuclides with half-lives greater than 20 years, and concentrations greater than 100 nCi/g (3.7 MBq/kg), excluding High Level Waste. Elements that have an atomic number greater than uranium are called transuranic ("beyond uranium"). Because of their long half-lives, TRUW is disposed more cautiously than either low level or intermediate level waste. In the U.S. it arises mainly from weapons production, and consists of clothing, tools, rags, residues, debris and other items contaminated with small amounts of radioactive elements (mainly plutonium).
Under U.S. law, TRUW is further categorized into "contact-handled" (CH) and "remote-handled" (RH) on the basis of radiation dose measured at the surface of the waste container. CH TRUW has a surface dose rate not greater than 200 mrem per hour (2 mSv/h), whereas RH TRUW has a surface dose rate of 200 mrem per hour (2 mSv/h) or greater. CH TRUW does not have the very high radioactivity of high level waste, nor its high heat generation, but RH TRUW can be highly radioactive, with surface dose rates up to 1000000 mrem per hour (10000 mSv/h). The United States currently permanently disposes of TRUW generated from nuclear power plants and military facilities at the Waste Isolation Pilot Plant.[11]
Of particular concern in nuclear waste management are two long-lived fission products, Tc-99 (half-life 220,000 years) and I-129 (half-life 17 million years), which dominate spent fuel radioactivity after a few thousand years. The most troublesome transuranic elements in spent fuel are Np-237 (half-life two million years) and Pu-239 (half life 24,000 years).[12] Nuclear waste requires sophisticated treatment and management in order to successfully isolate it from interacting with the biosphere. This usually necessitates treatment, followed by a long-term management strategy involving storage, disposal or transformation of the waste into a non-toxic form[13]. Governments around the world are considering a range of waste management and disposal options, though there has been limited progress toward long-term waste management solutions.[14]
Long-term storage of radioactive waste requires the stabilization of the waste into a form which will not react, nor degrade, for extended periods of time. One way to do this is through vitrification. Currently at Sellafield the high-level waste (PUREX first cycle raffinate) is mixed with sugar and then calcined. Calcination involves passing the waste through a heated, rotating tube. The purposes of calcination are to evaporate the water from the waste, and de-nitrate the fission products to assist the stability of the glass produced.
The 'calcine' generated is fed continuously into an induction heated furnace with fragmented glass[2]. The resulting glass is a new substance in which the waste products are bonded into the glass matrix when it solidifies. This product, as a molten fluid, is poured into stainless steel cylindrical containers ("cylinders") in a batch process. When cooled, the fluid solidifies ("vitrifies") into the glass. Such glass, after being formed, is very highly resistant to water. [15]
After filling a cylinder, a seal is welded onto the cylinder. The cylinder is then washed. After being inspected for external contamination, the steel cylinder is stored, usually in an underground repository. In this form, the waste products are expected to be immobilized for a very long period of time (many thousands of years).
The glass inside a cylinder is usually a black glossy substance. All this work (in the United Kingdom) is done using hot cell systems. The sugar is added to control the ruthenium chemistry and to stop the formation of the volatile RuO4 containing radio ruthenium. In the west, the glass is normally a borosilicate glass (similar to Pyrex), while in the former Soviet bloc it is normal to use a phosphate glass. The amount of fission products in the glass must be limited because some (palladium, the other Pt group metals, and tellurium) tend to form metallic phases which separate from the glass. In Germany a vitrification plant is in use; this is treating the waste from a small demonstration reprocessing plant which has since been closed down.
It is common for medium active wastes in the nuclear industry to be treated with ion exchange or other means to concentrate the radioactivity into a small volume. The much less radioactive bulk (after treatment) is often then discharged. For instance, it is possible to use a ferric hydroxide floc to remove radioactive metals from aqueous mixtures [3]. After the radioisotopes are absorbed onto the ferric hydroxide, the resulting sludge can be placed in a metal drum before being mixed with cement to form a solid waste form.[16] In order to get better long-term performance (mechanical stability) from such forms, they may be made from a mixture of fly ash, or blast furnace slag, and portland cement, instead of normal concrete (made with portland cement, gravel and sand).
The Australian Synroc (synthetic rock) is a more sophisticated way to immobilize such waste, and this process may eventually come into commercial use for civil wastes (it is currently being developed for U.S. military wastes). Synroc was invented by the late Prof Ted Ringwood (a geochemist) at the Australian National University.[17] The Synroc contains pyrochlore and cryptomelane type minerals. The original form of Synroc (Synroc C) was designed for the liquid high level waste (PUREX raffinate) from a light water reactor. The main minerals in this Synroc are hollandite (BaAl2Ti6O16), zirconolite (CaZrTi2O7) and perovskite (CaTiO3). The zirconolite and perovskite are hosts for the actinides. The strontium and barium will be fixed in the perovskite. The caesium will be fixed in the hollandite.
The timeframe in question when dealing with radioactive waste ranges from 10,000 to 1,000,000 years,[18] according to studies based on the effect of estimated radiation doses.[19] Hannes Alfvén, Nobel laureate in physics, described the as yet unsolved dilemma of radioactive waste management:
“The problem is how to keep radioactive waste in storage until it decays after hundreds of thousands of years. The geologic deposit must be absolutely reliable as the quantities of poison are tremendous. It is very difficult to satisfy these requirements for the simple reason that we have had no practical experience with such a long term project. Moreover permanently guarded storage requires a society with unprecedented stability.”[20]
Thus, Alfvén identified two fundamental prerequisites for effective management of high-level radioactive waste: (1) stable geological formations, and (2) stable human institutions over hundreds of thousands of years. However, no known human civilization has ever endured for so long. Moreover, no geologic formation of adequate size for a permanent radioactive waste repository has yet been discovered that has been stable for so long a period.
Researchers suggest that forecasts of health detriment for such periods should be examined critically[21]. Practical studies only consider up to 100 years as far as effective planning[22] and cost evaluations[23] are concerned. Long term behaviour of radioactive wastes remains a subject for ongoing research projects.[24]
High-level radioactive waste is stored temporarily in spent fuel pools and in dry cask storage facilities. This allows the shorter-lived isotopes to decay before any further handling.
The U.S. dumped radioactive waste into the Ocean until 1970, in Europe this was banned after 1982[25]
In 1997, in the 20 countries which account for most of the world's nuclear power generation, spent fuel storage capacity at the reactors was 148,000 tonnes, with 59% of this utilized. However, a number of nuclear power plants in countries that do not reprocess had nearly filled their spent fuel pools, and resorted to Away-from-reactor storage (AFRS). AFRS capacity in 1997 was 78,000 tonnes, with 44% utilized, and annual additions of about 12,000 tonnes. AFRS cannot be expanded forever, and the lead times for final disposal sites have proven to be unpredictable (see below).
In 1989 and 1992, France commissioned commercial plants to vitrify HLW left over from reprocessing oxide fuel, although there are adequate facilities elsewhere, notably in the United Kingdom and Belgium. The capacity of these western European plants is 2,500 canisters (1000 t) a year, and some have been operating for 18 years.
The process of selecting appropriate deep final repositories for high level waste and spent fuel is now under way in several countries with the first expected to be commissioned some time after 2010. The basic concept is to locate a large, stable geologic formation and use mining technology to excavate a tunnel, or large-bore tunnel boring machines (similar to those used to drill the Chunnel from England to France) to drill a shaft 500-1,000 meters below the surface where rooms or vaults can be excavated for disposal of high-level radioactive waste. The goal is to permanently isolate nuclear waste from the human environment. However, many people remain uncomfortable with the immediate stewardship cessation of this disposal system, suggesting perpetual management and monitoring would be more prudent.
Many years ago, Hannes Alfvén, Nobel laureate in physics, described the dilemma of permanent geological disposal:
According to Alfvén, there are two fundamental prerequisites for effective deep geologic management of high-level radioactive waste: (1) absolutley stable geological formations, and (2) unprecedented stability of human institutions over hundreds of thousands of years. However, no geologic formation of adequate size for a permanent repository yet discovered has been stable for so long a period. And no known human civilization has ever endured for so long.
Because some radioactive species have half-lives longer than one million years, even very low container leakage and radionuclide migration rates must be taken into account.[27] Moreover, it may require more than one half-life until some nuclear materials lose enough radioactivity to no longer be lethal to living things. A 1983 review of the Swedish radioactive waste disposal program by the National Academy of Sciences found that country’s estimate of several hundred thousand years--perhaps up to one million years-- being necessary for waste isolation “fully justified.”[28]
Storing high level nuclear waste above ground for a century or so is considered appropriate by many scientists. This allows the material to be more easily observed and any problems detected and managed, while decay of radionuclides over this time period significantly reduces the level of radioactivity and associated harmful effects to the container material. It is also considered likely that over the next century newer materials will be developed which will not break down as quickly when exposed to a high neutron flux, thus increasing the longevity of the container once it is permanently buried.
Sea-based options for disposal of radioactive waste [29]include burial beneath a stable abyssal plain, burial in a subduction zone that would slowly carry the waste downward into the Earth's mantle, and burial beneath a remote natural or human-made island. While these approaches all have merit and would facilitate an international solution to the vexing problem of disposal of radioactive waste, they are currently not being seriously considered because of the legal barrier of the Law of the Sea and because in North America and Europe sea-based burial has become taboo from fear that such a repository could leak and cause widespread damage. Dumping of radioactive waste from ships has reinforced this concern, as has contamination of islands in the Pacific Ocean. However, sea-based approaches might come under consideration in the future by individual countries or groups of countries that cannot find other acceptable solutions.
Article 1 (Definitions), 7., of the 1996 Protocol to the Convention on the Prevention of Marine Pollution by Dumping of Wastes and Other Matter, (the London Dumping Convention) states:
The proposed land-based subductive waste disposal method disposes of nuclear waste in a subduction zone accessed from land[30], and therefore is not prohibited by international agreement. This method has been described as the most viable means of disposing of radioactive waste,[31] and as the state-of-the-art in nuclear waste disposal technology.[32]
Another approach termed Remix & Return [33] would blend high-level waste with uranium mine and mill tailings down to the level of the original radioactivity of the uranium ore, then replace it in inactive uranium mines. This approach has the merits of providing jobs for miners who would double as disposal staff, and of facilitating a cradle-to-grave cycle for radioactive materials. However, this approach would be inappropriate for spent reactor fuel in the absence of reprocessing, due to the presence in it of highly toxic radioactive elements such as plutonium.
There have been proposals for reactors that consume nuclear waste and transmute it to other, less-harmful nuclear waste. In particular, the Integral Fast Reactor was a proposed nuclear reactor with a nuclear fuel cycle that produced no transuranic waste and in fact, could consume transuranic waste. It proceeded as far as large-scale tests but was then canceled by the U.S. Government. Another approach, considered safer but requiring more development, is to dedicate subcritical reactors to the transmutation of the left-over transuranic elements.
Transmutation was banned in the United States on April 1977 by President Carter due to the danger of plutonium proliferation[34], but President Reagan rescinded the ban in 1981 [35]. Due to the economic losses and risks, construction of reprocessing plants during this time did not resume. Due to high energy demand, work on the method has continued in the EU. This has resulted in a practical nuclear research reactor called Myrrha in which transmutation is possible. Additionally, a new research program called ACTINET has been started in the EU to make transmutation possible on a large, industrial scale. According to President Bush's Global Nuclear Energy Partnership (GNEP) of 2007, the United States is now actively promoting research on transmutation technologies needed to markedly reduce the problem of nuclear waste treatment. [36]
There have also been theoretical studies involving the use of fusion reactors as so called "actinide burners" where a fusion reactor plasma such as in a tokamak, could be "doped" with a small amount of the "minor" transuranic atoms which would be transmuted (meaning fissioned in the actinide case) to lighter elements upon their successive bombardment by the very high energy neutrons produced by the fusion of deuterium and tritium in the reactor. It was recently found by a study done at MIT, that only 2 or 3 fusion reactors with parameters similar to that of the International Thermonuclear Experimental Reactor (ITER) could transmute the entire annual minor actinide production from all of the light water reactors presently operating in the United States fleet while simultaneously generating approximately 1 gigawatt of power from each reactor[4].
Another option is to find applications of the isotopes in nuclear waste so as to re-use them[37]. Already, caesium-137, strontium-90 and a few other isotopes are extracted for certain industrial applications such as food irradiation and radioisotope thermoelectric generators. While re-use does not eliminate the need to manage radioisotopes, it may reduce the quantity of waste produced.
The Nuclear Assisted Hydrocarbon Production Method, [38]Canadian patent application 2,638,179, is a method for the temporary or permanent storage of nuclear waste materials comprising the placing of waste materials into one or more repositories or boreholes constructed into an unconventional oil formation. The thermal flux of the waste materials fracture the formation, alters the chemical and/or physical properties of hydrocarbon material within the subterranean formation to allow removal of the altered material. A mixture of hydrocarbons, hydrogen, and/or other formation fluids are produced from the formation. The radioactivity of high-level radioactive waste affords proliferation resistance to plutonium placed in the periphery of the repository or the deepest portion of a borehole.
Space disposal is an attractive notion because it permanently removes nuclear waste from the environment. However, it has significant disadvantages, not least of which is the potential for catastrophic failure of a launch vehicle. Furthermore, the high number of launches that would be required — due to the fact that no individual rocket would be able to carry very much of the material relative to the material needed to be disposed of—makes the proposal impractical (for both economic and risk-based reasons). To further complicate matters, international agreements on the regulation of such a program would need to be established. [5] This method would also be energetically intensive and thus is not necessarily economically feasible.
It has been suggested that through the use of a stationary launch system many of the risks of catastrophic launch failure could be avoided. A promising concept is the use of high power lasers to launch "indestructible" containers from the ground into space. Such a system would require no rocket propellant, with the launch vehicle's payload making up a near entirety of the vehicle's mass. Without the use of rocket fuel on board there would be little chance of the vehicle exploding.[6]
Another form of safe removal would possibly be the space elevator. Encasing the waste in glassified form inside a steel shell 9 inches (230 mm) thick, which in turn is tiled with shuttle tile to its exterior. If the launch vehicle fails just before reaching orbit, the waste ball will safely re-enter the earth's atmosphere. The steel shell would deform on impact, but would not rupture due to the density of the shell. Also, this would potentially allow the waste to be shot into the Sun.[39]
Most countries are considerably behind the United States in developing plans for high-level radioactive waste disposal. Sweden and Finland are furthest along in committing to a particular disposal technology, while many others reprocess spent fuel or contract with France or Great Britain to do it, taking back the resulting plutonium and high-level waste. “An increasing backlog of plutonium from reprocessing is developing in many countries... It is doubtful that reprocessing makes economic sense in the present environment of cheap uranium.”[40]
In many European countries (e.g., Britain, Finland, the Netherlands, Sweden and Switzerland) the risk or dose limit for a member of the public exposed to radiation from a future high-level nuclear waste facility is considerably more stringent than that suggested by the International Commission on Radiation Protection or proposed in the United States. European limits are often more stringent than the standard suggested in 1990 by the International Commission on Radiation Protection by a factor of 20, and more stringent by a factor of ten than the standard proposed by the U.S. Environmental Protection Agency (EPA) for Yucca Mountain for the first 10,000 years after closure. Moreover, the U.S. EPA’s proposed standard for greater than 10,000 years is 250 times more permissive than the European limit.[41]
A national Nuclear Fuel Waste Act was enacted by the Canadian Parliament in 2002, requiring nuclear energy corporations to create a waste management organization to propose to the Government of Canada approaches for management of nuclear waste, and implementation of an approach subsequently selected by the government. The Act defined management as “long term management by means of storage or disposal, including handling, treatment, conditioning or transport for the purpose of storage or disposal.”[42]
The resulting Nuclear Waste Management Organization in 2005 recommended centralized isolation of spent nuclear fuel in a deep geologic repository 500-1,000 meters underground in a suitable rock formation such as the granite of the Canadian Shield, or Ordovician sedimentary shale such as that underlying most of the province of Ontario, where most of the 18 operable Canadian nuclear reactors are located.[43] Vaults are to be dug inside geological formations known as batholiths, formed about a billion years ago. Used fuel bundles will be encased in a corrosion-resistant container, and further surrounded by a layer of buffer material, possibly of bentonite clay. The container is designed to last for thousands of years, while the clay would further slow corrosion rates of the container. The batholiths are chosen for their low ground-water movement rates, geological stability, and low economic value.[44]
Also recommended was a phased decision making process supported by a program of continuous learning, research and development. An interim step in implementation is shallow underground storage of spent fuel at the central site, prior to final placement in a deep repository. Reprocessing spent fuel was rejected due to the cost, production of waste materials even more difficult to manage, and the potential for separation and proliferation of weapons-grade plutonium.[45] A timeline for implementation of recommendations contained in the draft report has been described as “leisurely,” waiting for ten years to initiate site selection, deciding whether to construct a centralized storage facility in 20 years, suggesting placement of waste in a deep geologic repository would only begin in about 60 years.[46]
In the Peoples Republic of China, ten reactors provide about 2 percent of electricity and five more are under construction.[47] China made a commitment to reprocessing in the 1980s; a pilot plant is under construction at Lanzhou, where a temporary spent fuel storage facility has been constructed. Geological disposal has been studied since 1985, and a permanent deep geological repository was required by law in 2003. Sites in Gansu Province near the Gobi desert in northwestern China are under investigation, with a final site expected to be selected by 2020, and actual disposal by about 2050.[48]
In 1983, the government decided to select a site for permanent repository by 2010. With only four nuclear reactors providing 29 percent of its electricity,[49] Finland in 1987 enacted a Nuclear Energy Act making the producers of radioactive waste responsible for its disposal, subject to requirements of its Radiation and Nuclear Safety Authority and an absolute veto given to local governments in which a proposed repository would be located. Producers of nuclear waste organized Posiva Oy with responsibility for site selection, construction and operation of a permanent repository. A 1994 amendment to the Act required final disposal of spent fuel in Finland, prohibiting the import or export of radioactive waste.
Environmental assessment of four sites occurred in 1997-98, Posiva Oy chose the Olkiluoto site near two existing reactors, and the local government approved it in 2000. The Finnish Parliament approved a deep geologic repository there in igneous bedrock at a depth of about 500 meters in 2001. The repository concept is similar to the Swedish model, with containers to be clad in copper and buried below the water table beginning in 2020.[50] The Finnish government has started building a vault to store nuclear waste not far from the Olkiluoto Nuclear Power Plant.
With 59 nuclear reactors contributing about 75 percent of its electricity,[51] the highest percentage of any country, France has been reprocessing its spent reactor fuel since the introduction of nuclear power there. Some reprocessed plutonium is used to make fuel, but more is being produced than is being recycled as reactor fuel.[52] France also reprocesses spent fuel for other countries, but the nuclear waste is returned to the country of origin. Radioactive waste from reprocessing French spent fuel is expected to be disposed of in a geological repository, pursuant to legislation enacted in 1991 that established a 15 year period for conducting radioactive waste management research. Under this legislation, partition and transmutation of long-lived elements, immobilization and conditioning processes, and long-term near surface storage are being investigated by a Commissariat a l’Energy Atomique (CEA). Disposal in deep geological formations is being studied by the French agency for radioactive waste management, Agence Nationale pur la gestion des Dechets Radioactifs (ANDRA), in underground research labs.[53]
Three sites were identified for possible deep geologic disposal in clay near the border of Meuse and Haute-Marne, near Gard, and at Vienne. In 1998 the government approved the site near Meuse/Haute-Marne and dropped the others from further consideration. [54] Legislation was proposed in 2006 to license a repository by 2015, with operations expected in 2025.[55]
Nuclear waste policy in Germany is in flux. With 17 reactors in operation, accounting for about 30 percent of its electricity, [56] German planning for a permanent geologic repository began in 1974, focused on a salt mine near Gorleben about 100 kilometers northeast of Braunschweig. The site was announced in 1977 with plans for a reprocessing plant, spent fuel management, and permanent disposal facilities at a single site. Plans for the reprocessing plant were dropped in 1979. In 2000, the federal government and utilities agreed to suspend underground investigations for three to ten years, and the government committed to ending its use of nuclear power, closing one reactor in 2003.[57] In 2005 Angela Merkel was elected Chancellor with a promise to change the policy moving away from nuclear power, but was unsuccessful in doing so through November 2006.[58]
Meanwhile, electric utilities have been transporting spent fuel to interim storage facilities at Gorleben, Lubmin and Ahaus until temporary storage facilities can be built near reactor sites. Previously, spent fuel was sent to France or England for reprocessing, but this practice was ended in July 2005. [59]
Sixteen nuclear reactors produce about 3 percent of India’s electricity, and seven more are under construction.[60] Spent fuel is processed at facilities in Trombay near Mumbai, at Tarapur on the west coast north of Mumbai, and at Kalpakkam on the southeast coast of India. Plutonium will be used in a fast breeder reactor (under construction) to produce more fuel, and other waste vitrified at Tarapur and Trombay.[61][62] Interim storage for 30 years is expected, with eventual disposal in a deep geological repository in crystalline rock near Kalpakkam. [63]
With 55 nuclear reactors producing about 29 percent of its electricity,[64] the Japanese policy is to reprocess its nuclear waste. Originally spent fuel was reprocessed under contract in England and France, but after public outcry a major reprocessing plant was built in Rokkasho, with operations expected to commence in 2007.[65] The policy to use recovered plutonium as mixed oxide (MOX) reactor fuel was questioned on economic grounds because there are few reactors capable of using it, and in 2004 it was revealed the Ministry of Economy, Trade and Industry had covered up a 1994 report indicating reprocessing spent fuel would cost four times as much as burying it.[66]
In 2000, a Specified Radioactive Waste Final Disposal Act called for creation of a new organization to manage high level radioactive waste, and later that year the Nuclear Waste Management Organization of Japan (NUMO) was established under the jurisdiction of the Ministry of Economy, Trade and Industry. NUMO is responsible for selecting a permanent deep geologic repository site, construction, operation and closure of the facility for waste emplacement by 2040.[67][68] Site selection was begun in 2002 and application information was sent to 3,239 municipalities, but by spring 2006, no local government had volunteered to host the facility. Final selection of a repository location is expected between 2023 and 2027.[69]
In Russia, the Ministry of Atomic Energy (Minatom) is responsible for 31 nuclear reactors which generate about 16 percent of its electricity.[70] Minatom is also responsible for reprocessing and radioactive waste disposal, including over 25,000 tons of spent nuclear fuel in temporary storage in 2001.
Russia has a long history of reprocessing spent fuel for military purposes, and previously planned to reprocess imported spent fuel, possibly including some of the 33,000 metric tons of spent fuel accumulated at sites in other countries who received fuel from the U.S., which the U.S. originally pledged to take back, such as Brazil, the Czech Republic, India, Japan, Mexico, Slovenia, South Korea, Switzerland, Taiwan , and the European Union.[71][72]
An Environmental Protection Act in 1991 prohibited importing radioactive material for long-term storage or burial in Russia, but controversial legislation to allow imports for permanent storage was passed by the Russian Parliament and signed by President Putin in 2001.[73] In the long term, the Russian plan is for deep geologic disposal.[74] Most attention has been paid to locations where waste has accumulated in temporary storage at Mayak, near Chelyabinsk in the Ural Mountains, and in granite at Krasnoyarsk in Siberia.
In Sweden there are ten operating nuclear reactors that produce about 45 percent of its electricity.[75] Two other reactors in Barsebäck were shut down in 1999 and 2005.[76] When these reactors were built, it was expected their nuclear fuel would be reprocessed in a foreign country, and the reprocessing waste would not be returned to Sweden.[77] Later, construction of a domestic reprocessing plant was contemplated, but has not been built.
Passage of the Stipulation Act of 1977 transferred responsibility for nuclear waste management from the government to the nuclear industry, requiring reactor operators to present an acceptable plan for waste management with “absolute safety” in order to obtain an operating license.[78][79] In early 1980, after the Three Mile Island meltdown in the United States, a referendum was held on the future use of nuclear power in Sweden. In late 1980, after a three-question referendum produced mixed results, the Swedish Parliament decided to phase out existing reactors by 2010.[80]
The Swedish Nuclear Fuel and Waste Management Co. (Svensk Kärnbränslehantering AB, known as SKB), was created in 1980 and is responsible for final disposal of nuclear waste there. This includes operation of a monitored retrievable storage facility, the Central Interim Storage Facility for Spent Nuclear Fuel at Oskarshamn, about 150 miles south of Stockholm on the Baltic coast; transportation of spent fuel; and construction of a permanent repository.[81] Swedish utilities store spent fuel at the reactor site for one year before transporting it to the facility at Oskarshamn, where it will be stored in excavated caverns filled with water for about 30 years before removal to a permanent repository. Conceptual design of a permanent repository was determined by 1983, calling for placement of copper-clad iron canisters in granite bedrock about 1,650 feet underground, below the water table. Space around the canisters will be filled with bentonite clay.[82] After examining six possible locations for a permanent repository, three were nominated for further investigation at Osthammar, Oskarshamn, and Tierp. The first two are still under consideration, with a final selection expected no earlier than 2007.[83]
Spent nuclear fuel is stored for 1-10 years in water pools at Swiss reactors. An industry-owned organization, ZWILAG, built and operates Switzerland’s centralized interim storage facility for spent nuclear fuel, high-level radioactive waste, conditioning low-level radioactive waste, and for incinerating wastes. Other interim storage facilities predating ZWILAG continue to operate in Switzerland.
Switzerland has four nuclear reactors that provide about 43 percent of its electricity.[84] The Swiss contract for reprocessing spent nuclear fuel in France and the United Kingdom. Two deep repository options are under consideration for permanent high-level radioactive waste disposal, in crystalline rock and Opalinus clay. Construction of a repository is not foreseen until well into this century. The Grimsel Test Site is an international research facility investigating unresolved questions in radioactive waste disposal.[85]
Great Britain has 19 operating reactors, producing about 20 percent of its electricity.[86] It processes much of its spent fuel at Sellafield on the northwest coast across from Ireland, where nuclear waste is vitrified and sealed in stainless steel canisters for dry storage above ground for at least 50 years before eventual deep geologic disposal. Sellafield has a history of environmental and safety problems, including a fire in a nuclear plant in Windscale, and a significant incident in 2005 at the main reprocessing plant (THORP).[87]
In 1982 the Nuclear Industry Radioactive Waste Management Executive (NIREX) was established with responsibility for disposing of long-lived nuclear waste[88] and in 2006 a Committee on Radioactive Waste Management (CoRWM) of the Department of Environment, Food and Rural Affairs recommended geologic disposal 200-1,000 meters underground.[89] NIREX developed a generic repository concept based on the Swedish model[90] but has not yet selected a site. A Nuclear Decommissioning Authority is responsible for packaging waste from reprocessing and will eventually relieve British Nuclear Fuels Ltd. of responsibility for power reactors and the Sellafield reprocessing plant.[91]
The Nuclear Waste Policy Act of 1982 established a timetable and procedure for constructing a permanent, underground repository for high-level radioactive waste by the mid-1990s, and provided for some temporary storage of waste, including spent fuel from 104 civilian nuclear reactors that produce about 19.4 percent of electricity there.[92] The United States in April 2008 had about 56,000 metric tons of spent fuel and 20,000 canisters of solid defense-related waste, and this is expected to increase to 119,000 metric tons by 2035.[93] The U.S. has opted for a final repository at Yucca Mountain in Nevada, currently under construction, but this project is widely opposed, with some of the main concerns being long distance transportation of waste from across the United States to this site, the possibility of accidents, and the uncertainty of success in isolating nuclear waste from the human environment in perpetuity. Yucca Mountain is expected to have capacity for 70,000 metric tons of radioactive waste and is expected to open in 2017.[94] The Waste Isolation Pilot Plant in the United States is the world's first underground repository for transuranic waste.
Although Australia does not have any nuclear power reactors, Pangea Resources considered siting an international repository in the outback of South Australia or Western Australia in 1998, but this stimulated legislative opposition in both states and the Australian national Senate during the following year.[95] Thereafter, Pangea ceased operations in Australia but reemerged as Pangea International Association, and in 2002 evolved into the Association for Regional and International Underground Storage with support from Belgium, Bulgaria, Hungary, Japan and Switzerland.[96] A general concept for an international repository has been advanced by one of the principals in all three ventures.[97] Russia has expressed interest in serving as a repository for other countries, but does not envision sponsorship or control by an international body or group of other countries. South Africa, Argentina and western China have also been mentioned as possible locations.[98][99]
In the EU, Covra is negotiating about a European-wide waste disposal system with single disposal sites that can be used by several EU-countries.[100] This EU-wide storage possibility is being researched under the SAPIERR-2 program.[101]
A number of incidents have occurred when radioactive material was disposed of improperly, shielding during transport was defective, or when it was simply abandoned or even stolen from a waste store.[102] In the Soviet Union, waste stored in Lake Karachay was blown over the area during a dust storm after the lake had partly dried out.[103] At Maxey Flat, a low-level radioactive waste facility located in Kentucky, containment trenches covered with dirt, instead of steel or cement, collapsed under heavy rainfall into the trenches and filled with water. The water that invaded the trenches became radioactive and had to be disposed of at the Maxey Flat facility itself. In other cases of radioactive waste accidents, lakes or ponds with radioactive waste accidentally overflowed into the rivers during exceptional storms.
Scavenging of abandoned radioactive material has been the cause of several other cases of radiation exposure, mostly in developing nations, which may have less regulation of dangerous substances (and sometimes less general education about radioactivity and its hazards) and a market for scavenged goods and scrap metal. The scavengers and those who buy the material are almost always unaware that the material is radioactive and it is selected for its aesthetics or scrap value.[104] Irresponsibility on the part of the radioactive material's owners, usually a hospital, university or military, and the absence of regulation concerning radioactive waste, or a lack of enforcement of such regulations, have been significant factors in radiation exposures. For an example of an accident involving radioactive scrap originating from a hospital see the Goiânia accident.[104]
Transportation accidents involving spent nuclear fuel from power plants are unlikely to have serious consequences due to the strength of the spent nuclear fuel shipping casks.
In Italy, several radioactive waste deposits let material flow into river water, thus contaminating water fit for domestic use. [105]
In fiction, radioactive waste is often cited as the reason for gaining super-human powers and abilities.
An example of this fictional scenario is the 1981 movie "Modern Problems" in which actor Chevy Chase portrays a jealous, harried air traffic controller Max Fiedler. Fiedler, recently dumped by his girlfriend, comes into contact with nuclear waste and is granted the power of telekinesis, which he uses to not only win her back, but to gain a little revenge. In reality, of course, exposure to radioactive waste instead would lead to illness and/or death.
In the science fiction television series, "Space: 1999," a massive nuclear waste dump on the Moon explodes, hurtling the Moon, and the inhabitants of "Moonbase Alpha" out of the Solar System at interstellar speeds.
In the television comedy series Family Guy, the Griffin family all get super-human powers from toxic waste. When the local mayor Adam West tries to do the same thing, he gets lymphoma.
In The Simpsons, many mutant three-eyed fish live near the Springfield Nuclear Power Plant. The owner of the plant, Mr Burns, is also repeatedly shown disposing of his plant's waste in an improper manner, either dumping it in the river or hiding it in trees at the local park.
Radioactive waste in movies, television and comic books is often depicted as glowing sludge of various colors, usually bright green, and stored in large metal drums with the radiation hazard symbol.
In the movie Hills Have Eyes, the aberrant transmutations of the people in the New Mexico Desert were the result of a radioactive waste spill.
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