Vinyl fluoride

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Vinyl fluoride
IUPAC name Fluoroethene
Other names Vinylfluoride, Fluoroethylene, Monofluoroethylene, Vinyl fluoride monomer, VF, R 1141, UN 1860 (inhibited)
Identifiers
CAS number [75-02-5]
PubChem 6339
EINECS number 200-832-6
RTECS number YZ7351000
SMILES C=CF
InChI 1/C2H3F/c1-2-3/h2H,1H2
Properties
Molecular formula C2H3F
Molar mass 46.05 g/mol
Appearance Colorless gas with a faint, ethereal odor
Density 2 g/cm3 (gas)

0.91 g/cm3 (liquid)

Melting point

-160.5 °C (-257 °F)

Boiling point

-72.2 °C (98 °F)

Solubility in water Slightly soluble
Vapor pressure 25 500 kPa
Hazards
EU classification Extremely flammable (F+)
NFPA 704
4
1
2
 
R-phrases R12
S-phrases S9, S16, S33
Autoignition
temperature
385 °C
Explosive limits 2.6 - 21.7 %
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox disclaimer and references

Vinyl fluoride is an organic halide with the chemical formula C2H3F. It is a colorless gas with a faint etherlike odor.

Its critical point is at 54.8 °C (328 K) and 5.24 MPa. Dipole moment is 1.4 Debye and heat of vaporization is 361 kJ/kg.

It was first prepared in 1901 by Frédéric Swarts (the Belgian chemist who was the first to prepare CFCs in 1892) using the reaction of zinc with 1,1-difluoro-2-bromoethane. Now it is synthesized by the reaction of acetylene and hydrogen fluoride.

Its principal use is as the primary component in making polyvinyl fluoride, a polymer of the basic vinyl fluoride monomer.

Vinyl fluoride is classified as an IARC Group 2A carcinogen (likely to cause cancer in humans).

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