Uranium sulfate

From Wikipedia, the free encyclopedia

Uranium sulfate
Image:Uranium sulfate.jpg
Properties
Molecular formula U(SO4)2
Molar mass 430.15 g/mol
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox disclaimer and references

Uranium sulfate (U(SO4)2) is a water soluble salt of uranium. It is a very toxic compound and should not be ingested. Uranium sulfate minerals commonly are widespread around uranium bearing mine sites, where they usually form during the evaporation of acid sulfate-rich mine tailings which have been leached by oxygen-bearing waters. Uranium sulfate is a transitional compound in the production of Uranium hexafluoride. It was also used to fuel aqueous Homogeneous Reactors

[edit] Preparation

Uranyl sulfate in solution is readily photochemically reduced to uranium(IV) sulfate. The photoreduction can be carried out in the sunshine and this requires the addition of ethanol as a reducing agent. Uranium(IV) crystallizes or is precipitated by ethanol in excess. It can be obtained with different degrees of hydration.

[edit] References

  • Mata F., Martín-Gil J. and Martín-Gil F.J. (1980). "Preparation, infrared and visible spectra of sulfate complexes of uranium(IV)". Z. anorg. allg. Chem 462: 231–240. doi:10.1002/zaac.19804620127.