Uranium carbide

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Uranium carbide
Image:Uranium carbide.jpg
IUPAC name	Uranium carbide
Identifiers
CAS number	[12070-09-6]
Properties
Molecular formula	UC
Molar mass	250.04 g/mol
Density	11.3 g/cm³
Melting point	2790 °C
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references

Uranium carbide, a carbide of uranium, is a hard refractive ceramic material. It comes in several stoichiometries (U C_x), such as uranium monocarbide (UC, CAS number 12070-09-6), uranium sesquicarbide (U₂C₃, CAS number 12076-62-9), and uranium dicarbide (UC₂, CAS number 12071-33-9).

Like uranium dioxide and some other uranium compounds, uranium carbide can be used as a nuclear fuel for nuclear reactors, usually in the form of pellets or tablets. Uranium carbide fuel was used in late designs of nuclear thermal rockets.

Uranium carbide pellets are used as fuel kernels for the US version of pebble bed reactors; German version uses uranium dioxide instead.

As nuclear fuel, uranium carbide can be used either on its own, or mixed with plutonium carbide (PuC and Pu₂C₃). The mixture is also labeled as uranium-plutonium carbide (UPuC).

Uranium carbide is also a popular target material for particle accelerators.

Ammonia synthesis from nitrogen and hydrogen is sometimes accomplished in the presence of uranium carbide acting as a catalyst. (Hutchings, G. J., et al., AUranium-Oxide-Based Catalysts for the Destruction of Volatile Chloro-Organic compounds,@ Nature, 384, pp. 341B343, 1996.)

[edit] Solid state chemistry

Uranium dicarbide was reported by A.L. Bowman, G.P. Arnold, W.G. Witteman, T.C. Wallace and N.G. Nereson, Acta Crystallographica, 1966, 21, 670-671.

Diuranium tricarbide was reported by A.E. Austin, Acta Crystallographica, 1959, 12, 159-161.

[edit] References

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