Thallium(III) oxide

From Wikipedia, the free encyclopedia

Thallium(III) oxide
Image:Thallium(III) oxide.jpg
Other names thallium trioxide
Identifiers
CAS number [1314-32-5]
Properties
Molecular formula Tl2O3
Molar mass 456.7648 g/mol
Appearance brown-black odorless powder
Density 9.52 g/cm³, solid (16°C)
Melting point

717°C

Boiling point

1080°C

Solubility in water insoluble
Hazards
EU classification not listed
NFPA 704
 
3
 
 
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox disclaimer and references

Thallium(III) oxide is a chemical compound of thallium and oxygen. It occurs in nature as the mineral avicennite. Its structure is related to that of Mn2O3 which has a bixbyite like structure. Tl2O3 is metallic with high conductivity and is a degenerate n-type semiconductor which may have potential use in solar cells.[1] A method of producing Tl2O3 by MOCVD is known.[2] Any practical use of thallium(III) oxide will always have to take account of thalliums poisonous nature. Conditions/substances to avoid are: moisture and acids.

[edit] References

  1. ^ Phillips R. J., Shane M. J., Switzer J. A. (1989). "Electrochemical and photoelectrochemical deposition of Thallium(III) Oxide thin films". Journal of Materials Research 4: 923. doi:10.1557/JMR.1989.0923. 
  2. ^ D. Berry, R. T. Holm, R. L. Mowery, N. H. Turner, and M. Fatemi (1991). "Thallium(III) Oxide by Organometallic Chemical Vapor Deposition". Chemistry of Materials 3 (1): 72–77. doi:10.1021/cm00013a019. 
Languages