Thallium(III) oxide
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Thallium(III) oxide | |
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Image:Thallium(III) oxide.jpg | |
Other names | thallium trioxide |
Identifiers | |
CAS number | [1314-32-5] |
Properties | |
Molecular formula | Tl2O3 |
Molar mass | 456.7648 g/mol |
Appearance | brown-black odorless powder |
Density | 9.52 g/cm³, solid (16°C) |
Melting point |
717°C |
Boiling point |
1080°C |
Solubility in water | insoluble |
Hazards | |
EU classification | not listed |
NFPA 704 | |
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references |
Thallium(III) oxide is a chemical compound of thallium and oxygen. It occurs in nature as the mineral avicennite. Its structure is related to that of Mn2O3 which has a bixbyite like structure. Tl2O3 is metallic with high conductivity and is a degenerate n-type semiconductor which may have potential use in solar cells.[1] A method of producing Tl2O3 by MOCVD is known.[2] Any practical use of thallium(III) oxide will always have to take account of thalliums poisonous nature. Conditions/substances to avoid are: moisture and acids.
[edit] References
- ^ Phillips R. J., Shane M. J., Switzer J. A. (1989). "Electrochemical and photoelectrochemical deposition of Thallium(III) Oxide thin films". Journal of Materials Research 4: 923. doi: .
- ^ D. Berry, R. T. Holm, R. L. Mowery, N. H. Turner, and M. Fatemi (1991). "Thallium(III) Oxide by Organometallic Chemical Vapor Deposition". Chemistry of Materials 3 (1): 72–77. doi: .