Stannane
From Wikipedia, the free encyclopedia
Stannane | |
---|---|
IUPAC name | tin(IV) hydride |
Other names | tin tetrahydride tin hydride stannane |
Identifiers | |
CAS number | [2406-52-2] |
Properties | |
Molecular formula | SnH4 |
Molar mass | 122.71 g mol−1 |
Appearance | colourless gas |
Density | 5.4 g dm−3, gas |
Melting point |
−146 °C (127.15 K) |
Boiling point |
−52 °C (221.15 K) |
Solubility in water | ? g/100 ml (?°C) |
Related compounds | |
Related organotins | tributylstannane, Bu3SnH |
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references |
Stannane (SnH4) is the hydride of tin. Stannane can be prepared by the reaction of SnCl4 and LiAlH4.[1] Stannane decomposes slowly at room temperature to give metallic tin and hydrogen and ignites on contact with air.[1]
Variants of stannane can be found as a highly toxic, gaseous, inorganic metal hydride.
[edit] See also
[edit] References
- ^ a b Greenwood, N. N.; Earnshaw, A. (1997). Chemistry of the Elements, 2nd Edition, Oxford:Butterworth-Heinemann. ISBN 0-7506-3365-4.