Rotating wave approximation

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The rotating wave approximation is an approximation used in atom optics and magnetic resonance. In this approximation, terms in a Hamiltonian which oscillate rapidly are neglected. This is a valid approximation when the applied electromagnetic radiation is near resonance with an atomic resonance, and the intensity is low. Explicitly, terms in the Hamiltonians which oscillate with frequencies ωL + ω0 are neglected, while terms which oscillate with frequencies ωL − ω0 are kept, where ωL is the light frequency and ω0 is a transition frequency.

The name of the approximation stems from the form of the Hamiltonian in the interaction picture, as shown below. By switching to this picture the evolution of an atom due to the corresponding atomic Hamiltonian is absorbed into the system ket, leaving only the evolution due to the interaction of the atom with the light field to consider. It is in this picture that the rapidly-oscillating terms mentioned previously can be neglected. Since in some sense the interaction picture can be thought of as rotating with the system ket only that part of the electromagnetic wave that approximately co-rotates is kept; the counter-rotating component is discarded.

[edit] Mathematical formulation

For simplicity consider a two-level atomic system with excited and ground states |\text{e}\rangle and |\text{g}\rangle respectively (using the Dirac bracket notation). Let the energy difference between the states be \hbar\omega_0 so that ω0 is the transition frequency of the system. Then the unperturbed Hamiltonian of the atom can be written as

H_0=\hbar\omega_0|\text{e}\rangle\langle\text{e}|

Suppose the atom is placed at z = 0 in an external (classical) electric field of frequency ωL, given by \vec{E}(z,t)=\vec{E}_0(z)e^{-i\omega_Lt}+\vec{E}_0^*(z)e^{i\omega_Lt} (so that the field contains both positive- and negative-frequency modes in general). Then under the dipole approximation the interaction Hamiltonian can be expressed as

H_I=-\vec{d}\cdot\vec{E}

where \vec{d} is the dipole moment operator of the atom. The total Hamiltonian for the atom-light system is therefore H = H0 + HI. The atom does not have a dipole moment when it is in an energy eigenstate, so \langle\text{e}|\vec{d}|\text{e}\rangle=\langle\text{g}|\vec{d}|\text{g}\rangle=0. This means that defining \vec{d}_{\text{eg}}:=\langle\text{e}|\vec{d}|\text{g}\rangle allows the dipole operator to be written as

\vec{d}=\vec{d}_{\text{eg}}|\text{e}\rangle\langle\text{g}|+\vec{d}_{\text{eg}}^*|\text{g}\rangle\langle\text{e}|

(with ` * ' denoting the Hermitian conjugate). The interaction Hamiltonian can then be shown to be (see the Derivations section below)

H_I=-\hbar\left(\Omega e^{-i\omega_Lt}+\tilde{\Omega}e^{i\omega_Lt}\right)|\text{e}\rangle\langle\text{g}| -\hbar\left(\tilde{\Omega}^*e^{-i\omega_Lt}+\Omega^*e^{i\omega_Lt}\right)|\text{g}\rangle\langle\text{e}|

where Ω is the Rabi frequency and \tilde{\Omega}:=\hbar^{-1}\vec{d}_\text{eg}\cdot\vec{E}_0^* is the counter-rotating frequency. To see why the \tilde{\Omega} terms are called `counter-rotating' consider a unitary transformation to the interaction or Dirac picture where the transformed Hamiltonian \bar{H} is given by

\bar{H}=-\hbar\left(\Omega e^{-i\Delta t}+\tilde{\Omega}e^{i(\omega_L+\omega_0)t}\right)|\text{e}\rangle\langle\text{g}| -\hbar\left(\tilde{\Omega}^*e^{-i(\omega_L+\omega_0)t}+\Omega^*e^{i\Delta t}\right)|\text{g}\rangle\langle\text{e}|,

where Δ: = ωL − ω0 is the detuning of the light field.

[edit] Making the approximation

This is the point at which the rotating wave approximation is made. The dipole approximation has been assumed, and for this to remain valid the electric field must be near resonance with the atomic transition. This means that \Delta\ll\omega_L+\omega_0 and the complex exponentials multiplying \tilde{\Omega} and \tilde{\Omega}^* can be considered to be rapidly oscillating. Hence on any appreciable time scale the oscillations will quickly average to 0. The rotating wave approximation is thus the claim that these terms are negligible and the Hamiltonian can be written in the interaction picture as

\bar{H}_\text{RWA}=-\hbar\Omega e^{-i\Delta t}|\text{e}\rangle\langle\text{g}| -\hbar\Omega^*e^{i\Delta t}|\text{g}\rangle\langle\text{e}|.

Finally, in the Schrödinger picture the Hamiltonian is given by

H_\text{RWA}=\hbar\omega_0|\text{e}\rangle\langle\text{e}| -\hbar\Omega e^{-i\omega_Lt}|\text{e}\rangle\langle\text{g}| -\hbar\Omega^*e^{i\omega_Lt}|\text{g}\rangle\langle\text{e}|.


At this point the rotating wave approximation is complete. A common first step beyond this is to remove the remaining time dependence in the Hamiltonian via another unitary transformation.

[edit] Derivations

Given the above definitions the interaction Hamiltonian is

\begin{align} H_I &= -\vec{d}\cdot\vec{E} \\ &=-\left(\vec{d}_\text{eg}|\text{e}\rangle\langle\text{g}|+\vec{d}_\text{eg}^*|\text{g}\rangle\langle\text{e}|\right) \cdot\left(\vec{E}_0e^{-i\omega_Lt}+\vec{E}_0^*e^{i\omega_Lt}\right) \\ &=-\left(\vec{d}_\text{eg}\cdot\vec{E}_0e^{-i\omega_Lt} +\vec{d}_\text{eg}\cdot\vec{E}_0^*e^{i\omega_Lt}\right)|\text{e}\rangle\langle\text{g}| -\left(\vec{d}_\text{eg}^*\cdot\vec{E}_0e^{-i\omega_Lt} +\vec{d}_\text{eg}^*\cdot\vec{E}_0^*e^{i\omega_Lt}\right)|\text{g}\rangle\langle\text{e}| \\ &=-\hbar\left(\Omega e^{-i\omega_Lt}+\tilde{\Omega}e^{i\omega_Lt}\right)|\text{e}\rangle\langle\text{g}| -\hbar\left(\tilde{\Omega}^*e^{-i\omega_Lt}+\Omega^*e^{i\omega_Lt}\right)|\text{g}\rangle\langle\text{e}|, \end{align}

as stated. The next stage is to find the Hamiltonian in the interaction picture, \bar{H}. The unitary operator required for the transformation is U=e^{iH_0t/\hbar}, and an arbitrary state |\psi\rangle transforms to |\bar{\psi}\rangle=U|\psi\rangle. The Schrödinger equation must still hold in this new picture, so

\bar{H}|\bar{\psi}\rangle =i\hbar\partial_t|\bar{\psi}\rangle =i\hbar\dot{U}|\psi\rangle+Ui\hbar\partial_t|\psi\rangle =\left(i\hbar\dot{U}+UH\right)|\psi\rangle =\left(i\hbar\dot{U}U^\dagger+UHU^\dagger\right)|\bar{\psi}\rangle,

where a dot denotes the time derivative. This shows that the new Hamiltonian is given by

\begin{align} \bar{H}&=i\hbar\dot{U}U^\dagger+UHU^\dagger =i\hbar\left(\frac{i}{\hbar}UH_0\right)U^\dagger+U(H_0+H_I)U^\dagger =UH_IU^\dagger \\ &=-e^{i\omega_gt|\text{g}\rangle\langle\text{g}| + i\omega_et|\text{e}\rangle\langle\text{e}|}\left( \hbar\left(\Omega e^{-i\omega_Lt}+\tilde{\Omega}e^{i\omega_Lt}\right)|\text{e}\rangle\langle\text{g}| +\hbar\left(\tilde{\Omega}^*e^{-i\omega_Lt}+\Omega^*e^{i\omega_Lt}\right)|\text{g}\rangle\langle\text{e}|\right) e^{-i\omega_gt|\text{g}\rangle\langle\text{g}| - i\omega_et|\text{e}\rangle\langle\text{e}|}\\ &=-e^{i\,0\,t|\text{g}\rangle\langle\text{g}| + i\omega_0t|\text{e}\rangle\langle\text{e}|}\left( \hbar\left(\Omega e^{-i\omega_Lt}+\tilde{\Omega}e^{i\omega_Lt}\right)|\text{e}\rangle\langle\text{g}| +\hbar\left(\tilde{\Omega}^*e^{-i\omega_Lt}+\Omega^*e^{i\omega_Lt}\right)|\text{g}\rangle\langle\text{e}|\right) e^{-i\,0\,t|\text{g}\rangle\langle\text{g}| - i\omega_0t|\text{e}\rangle\langle\text{e}|}\\ &=-e^{i\omega_0t|\text{e}\rangle\langle\text{e}|}\left( \hbar\left(\Omega e^{-i\omega_Lt}+\tilde{\Omega}e^{i\omega_Lt}\right)|\text{e}\rangle\langle\text{g}| +\hbar\left(\tilde{\Omega}^*e^{-i\omega_Lt}+\Omega^*e^{i\omega_Lt}\right)|\text{g}\rangle\langle\text{e}|\right) e^{-i\omega_0t|\text{e}\rangle\langle\text{e}|}\\ \end{align}

Using a Taylor series expansion of the exponential,

\begin{align} e^{i\omega_0t|\text{e}\rangle\langle\text{e}|} = 1 + i\omega_0t|\text{e}\rangle\langle\text{e}| + \ldots \end{align}

and operating on \begin{align}|\text{e}\rangle\langle\text{g}| , \end{align}

\begin{align} e^{i\omega_0t|\text{e}\rangle\langle\text{e}|}|\text{e}\rangle\langle\text{g}| &= (1 + i\omega_0t|\text{e}\rangle\langle\text{e}| + \ldots)|\text{e}\rangle\langle\text{g}| \\ &= |\text{e}\rangle\langle\text{g}| + i\omega_0t|\text{e}\rangle\langle\text{g}| + \ldots \\ &= (1 + i\omega_0t + \ldots)|\text{e}\rangle\langle\text{g}| \\ &= e^{i\omega_0t}|\text{e}\rangle\langle\text{g}| . \\ \end{align}

Operating from the left on the second term of H above yields zero by orthogonality of |\text{g}\rangle and |\text{e}\rangle, and the same results apply to the operation of the second exponential from the right. Thus, the new Hamiltonian becomes

\begin{align} \bar{H}&=-\hbar\left(\Omega e^{-i\omega_Lt}+\tilde{\Omega}e^{i\omega_Lt}\right)e^{i\omega_0t}|\text{e}\rangle\langle\text{g}| -\hbar\left(\tilde{\Omega}^*e^{-i\omega_Lt}+\Omega^*e^{i\omega_Lt}\right)|\text{g}\rangle\langle\text{e}|e^{-i\omega_0t} \\ &=-\hbar\left(\Omega e^{-i\Delta t}+\tilde{\Omega}e^{i(\omega_L+\omega_0)t}\right)|\text{e}\rangle\langle\text{g}| -\hbar\left(\tilde{\Omega}^*e^{-i(\omega_L+\omega_0)t}+\Omega^*e^{i\Delta t}\right)|\text{g}\rangle\langle\text{e}|\ . \end{align}

The penultimate equality can be easily seen from the series expansion of the exponential map and the fact that \langle\text{i}|\text{j}\rangle=\delta_\text{ij} for i and j each equal to e or g (and δij the Kronecker delta).

The final step is to transform the approximate Hamiltonian back to the Schrödinger picture. The first line of the previous calculation shows that \bar{H}=UH_IU^\dagger, so in the same manner as the last calculation,

\begin{align} H_{I,\text{RWA}}&=U^\dagger\bar{H}_\text{RWA}U =e^{-i\omega_0t|\text{e}\rangle\langle\text{e}|} \left(-\hbar\Omega e^{-i\Delta t}|\text{e}\rangle\langle\text{g}| -\hbar\Omega^*e^{i\Delta t}|\text{g}\rangle\langle\text{e}|\right) e^{i\omega_0t|\text{e}\rangle\langle\text{e}|} \\ &=-\hbar\Omega e^{-i\Delta t}e^{-i\omega_0t}|\text{e}\rangle\langle\text{g}| -\hbar\Omega^*e^{i\Delta t}|\text{g}\rangle\langle\text{e}|e^{i\omega_0t} \\ &=-\hbar\Omega e^{-i\omega_Lt}|\text{e}\rangle\langle\text{g}| -\hbar\Omega^*e^{i\omega_Lt}|\text{g}\rangle\langle\text{e}|. \end{align}

The atomic Hamiltonian was unaffected by the approximation, so the total Hamiltonian in the Schrödinger picture under the rotating wave approximation is

H_\text{RWA}=H_0+H_{I,\text{RWA}} = \hbar\omega_0|\text{e}\rangle\langle\text{e}| -\hbar\Omega e^{-i\omega_Lt}|\text{e}\rangle\langle\text{g}| -\hbar\Omega^*e^{i\omega_Lt}|\text{g}\rangle\langle\text{e}|.