Pyrogallol

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Pyrogallol
Pyrogallol
Other names 1,2,3-Trihydroxybenzene
Pyrogallic acid
Identifiers
CAS number [87-66-1]
SMILES OC1=C(O)C=CC=C1O
Properties
Molecular formula C6H6O3
Molar mass 126.11 g/mol
Density 1.45 g/cm3
Melting point

131-134 °C

Boiling point

309 °C

Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox disclaimer and references

Pyrogallol or benzene-1,2,3-triol is a white crystalline powder and a powerful reducing agent. It was first prepared by Scheele 1786 by heating gallic acid. An alternate preparation is heating para-chlorophenoldisulphonic acid with potassium hydroxide.

When in alkaline solution, it absorbs water readily, turning purple from a colourless solution. It can also absorb oxygen and is used to calculate the amount of oxygen in air.

One can find its uses in hair dying, dying of suturing materials and for oxygen absorption in gas analysis. It also has antiseptic properties. Pyrogallol was also used as a developing agent in black-and-white developers, but its use is largely historical except for special purpose applications. (Hydroquinone is more commonly used today.)

Limited exposure to this compound is recommended. Pyrogallol is not likely to be used as a modern hair dye due to the suspected toxicity of the compound.

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