Mercury(II) iodide

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Mercury(II) iodide
Other names mercuric iodide
mercury biniodide
Identifiers
CAS number [7774-29-0]
Properties
Molecular formula HgI2
Molar mass 454.40 g/mol
Appearance scarlet red powder
Density 6.36 g/cm³, solid
Melting point

259°C

Boiling point

350°C (sublimes)

Solubility in water 6mg/100g water
Hazards
NFPA 704
 
3
 
 
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox disclaimer and references

Mercury(II) iodide (HgI2) is a chemical compound with an appearance of red-orange crystals. Unlike mercury(II) chloride it is hardly soluble in water (<100 ppm).

Conditions/substances to avoid include: heat, light, bromides, chlorides, ammonia, alkalis, cyanides, copper salts, lead salts, iodoform and hydrogen peroxide.

Mercury(II) iodide displays thermochromism; when heated above 126 °C, it undergoes phase transition from the alpha crystalline form to a pale yellow beta form. As the sample cools, it gradually reacquires its original color. It is often used for thermochromism demonstrations. [1]

Mercury(II) iodide is used for preparation of Nessler's reagent, used for detection of presence of ammonia.

Mercury(II) iodide is a semiconductor material, used in some x-ray and gamma ray detection and imaging devices operating at room temperatures. [2]

In medicine, mercury(II) iodide was formerly used as a treatment for syphilis.

In veterinary medicine, mercury(II) iodide is used in blister ointments in exostoses, bursal enlargement, etc.

Mercury(II) iodide is one of the stated possibilities for the "red mercury".

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