Manganese(II) sulfate

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Manganese(II) sulfate
IUPAC name	Manganese(II) sulfate
Other names	Manganese (II) sulphate
Identifiers
CAS number	[7785-87-7]
Properties
Molecular formula	MnSO4
Molar mass	Anhydrous 151.00 g/mol Tetrahydrate 223.07 g/mol
Density	2.95 g/cm3, ?
Melting point	700 °C; loses water at 400 ~ 500 °C
Boiling point	850 °C
Solubility in water	39.3 g/100 mL (24 °C); 26.2 g/100 mL (100 °C)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references

Manganese(II) sulfate is the inorganic compound with the formula MnSO₄. This colourless deliquescent solid is a commercially significant manganese(II) salt. Approximately 260M kg/y were produced worldwide in 2005.^[1] It is the precursor to manganese metal and many chemical compounds. Mn-deficient soil is remediated with this salt.

Like many metal sulfates, manganese sulfate forms a variety of hydrates: monohydrate, tetrahydrate, pentahydrate, heptahydrate. The monohydrate is most common. All of these salts are faintly pink. The pale color of Mn(II) salts is characteristic of high-spin complexes with the d⁵ configuration.

[edit] Applications and production

Typically manganese ores are purified by their conversion to manganese sulfate. Treatment of aqueous solutions of the sulfate with sodium carbonate leads to precipitation of manganese carbonate, which can be calcined to give the oxides MnO_x. Manganese dioxide reacts with sulfur dioxide also affords manganese sulfate:^[2]

MnO₂ + SO₂ → MnSO₄

Manganese sulfate is a by-product of various industrially significant oxidations that use manganese dioxide, including the manufacture of hydroquinone and anisaldehyde.^[1]

Treatment of manganese sulfate with potassium permanganate affords manganese dioxide, a component of dry-cell batteries.

[edit] References