Lithium sulfide
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Lithium Sulfide | |
---|---|
IUPAC name | Dilithium sulfanide |
Other names | Dilithium sulfide |
Identifiers | |
CAS number | [12136-58-2] |
PubChem | |
EINECS number | |
Properties | |
Molecular formula | Li2S |
Molar mass | 45.947(9) gmol-1 |
Appearance | white solid |
Density | 1.66 gcm-3, 1.64 gcm-3 |
Melting point |
938 °C (1211 K) |
Boiling point |
1372 °C (1645 K) |
Related compounds | |
Other anions | Lithium oxide |
Other cations | Sodium sulfide Potassium sulfide |
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references |
Lithium sulfide is the inorganic compound with the formula Li2S. This solid, which crystallises in the antifluorite motif, is described as the salt (Li+)2S2-. In 2005, lithium sulfide found use in batteries, the system being related to the sodium-sulfur battery.
Lithium sulfide is prepared by treating lithium with sulfur.[1]
This reaction is conveniently conducted in anhydrous ammonia.- 16Li + S8 → 8Li2S
[edit] References
- ^ Rankin, D. W. "Digermanyl Sulfide" Inorganic Syntheses 1974, XV, pages 182-184.
- ^ Webelements – Lithium Sulfide. Retrieved on 2005-09-16.
- ^ An article on lithium sulfide in batteries from Electronics Weekly. Retrieved on 2005-09-16.