Lithium sulfide

From Wikipedia, the free encyclopedia

Lithium Sulfide
IUPAC name Dilithium sulfanide
Other names Dilithium sulfide
Identifiers
CAS number [12136-58-2]
PubChem 64734
EINECS number 235-228-1
Properties
Molecular formula Li2S
Molar mass 45.947(9) gmol-1
Appearance white solid
Density 1.66 gcm-3, 1.64 gcm-3
Melting point

938 °C (1211 K)

Boiling point

1372 °C (1645 K)

Related compounds
Other anions Lithium oxide
Other cations Sodium sulfide
Potassium sulfide
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox disclaimer and references

Lithium sulfide is the inorganic compound with the formula Li2S. This solid, which crystallises in the antifluorite motif, is described as the salt (Li+)2S2-. In 2005, lithium sulfide found use in batteries,[1] the system being related to the sodium-sulfur battery.

Lithium sulfide is prepared by treating lithium with sulfur.[2] This reaction is conveniently conducted in anhydrous ammonia.[1]

16Li + S8 → 8Li2S

[edit] References

  1. ^ Rankin, D. W. "Digermanyl Sulfide" Inorganic Syntheses 1974, XV, pages 182-184.
  1. ^  Webelements – Lithium Sulfide. Retrieved on 2005-09-16.
  2. ^  An article on lithium sulfide in batteries from Electronics Weekly. Retrieved on 2005-09-16.

[edit] External Information

Lithium Sulfide

Languages