Lithium nitrate

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Lithium nitrate
Properties
Molecular formula LiNO3
Molar mass 68.946 g/mol
Appearance White to light yellow solid
Melting point

255 °C, 528 K, 491 °F

Boiling point

873 °C (decomposes)

Hazards
Main hazards Causes irritation
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox disclaimer and references

Lithium nitrate is an oxidizing agent used in the manufacture of red-colored fireworks and flares. It is deliquescent. The lithium cation being so small, makes it very polarizing, which explains why it is the least thermally stable group I nitrate.

Thermal decomposition occurs to give lithium oxide (Li2O), Nitric Oxide gas (NO2) and oxygen (O2):

4 LiNO3(s) → 2 Li2O(s) + 4 NO2(g) + O2(g)

This decomposition differs from the other group I nitrates, which decompose to form a nitrite and oxygen.

When held up to a flame, lithium nitrate makes the flame turn bright red. This compound is neutral.

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