- Ben Thompson - Consultant
- Dustin Lee Abraham - screenwriter and producer for CSI: Crime Scene Investigation
- Steve Allen - writer, comedian, musician
- Alvin Eli Amason - painter and sculptor
- Adam Archuleta - NFL player
- Jules Asner - TV Personality, Actress, Model
- Sal Bando - former MLB player
- Wes Bergmann - Cast member of The Real World: Austin ; Winner of the Real World/Road Rules Challenge: The Duel
- Bruce Blakeman- New York Politician, Lawyer,Power Broker,Commentator (class of 1980)
- Willie Bloomquist- MLB player for the Seattle Mariners
- Barry Bonds - MLB player who holds the all-time Major League Baseball home run record
- Amanda Borden - 1996 Summer Olympics team gold medal winner in gymnastics
- Amanda Brown - author of Legally Blonde
- William P. Carey - founder and chairman of W. P. Carey & Co. LLC
- Henry Carr - winner of two gold medals at the 1964 Summer Olympics
- Paul Casey - professional golfer
- Chris Cohan - founder, Sonic Communications; owner, Golden State Warriors
- Jack Clark- respected behavioral health professional and educator Phoenix Arizona
- Eric Crown - chairman of the board and co-founder, Insight Enterprises
- Ed Dee - author
- Ike Diogu - NBA player
- Jerry Dumas - comics writer and artist of Sam's Strip and Sam and Silo
- Mike Esposito - Major League Baseball pitcher for the Colorado Rockies.
- Andre Ethier - outfielder with the Los Angeles Dodgers of MLB.
- Justin Firestone- Minority Owner of the Arizona Diamondbacks
- David Fulcher - former National Football League defensive back
- Ira A. Fulton - businessman, founder of Fulton Homes
- Larry Gura - former All-Star MLB pitcher, played for the Chicago Cubs, New York Yankees, and Kansas City Royals.
- Carl Hayden - former U.S. Senator and Arizona's first Congressional Representative. Normal school graduate, class of 1896.
- Todd Heap - NFL player
- Cecil Heftel - founder Heftel Broadcasting; former U.S. Representative
- James Herndon - media psychologist
- Doug Hopkins - former lead guitarist and principal songwriter, Gin Blossoms
- Eddie House - NBA player
- Reggie Jackson - former MLB player, member of the Baseball Hall of Fame
- Paul Justin - retired National Football League quarterback
- Jimmy Kimmel - talk-show host and comedian
- Ian Kinsler - major league baseball player (attended)
- Bill Leen - bass player, Gin Blossoms
- Paul Lo Duca - MLB catcher for the New York Mets
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- Billy Mayfair - professional golfer
- Al Michaels - television broadcaster
- Phil Mickelson - professional golfer
- Harry Mitchell - U.S. Congressman, former Mayor of Tempe, former state Senator
- Paul "P.H." Naffah - Drummer for The Refreshments and Roger Clyne and The Peacemakers, Kappa Sigma
- Jim Palmer - former MLB player, member of the Baseball Hall of Fame, significant Sigma Chi
- Ed Pastor - U.S. Congressman
- Ken Phelps - radio broadcaster, former MLB player
- Jake Plummer - NFL player
- Tom Purtzer - professional golfer
- Michael Reagan - Son of former U.S. President Ronald Reagan
- Robert Rey - plastic surgeon, television personality (Dr. 90210)
- Gerald Riggs - Former NFL running back
- Brenna Sakas - Miss Arizona USA 2006
- Matt Salmon - former U.S. Congressman and gubernatorial candidate for Arizona
- Byron Scott - head coach, New Orleans Hornets; former NBA player
- Jimmy Siemers - professional water skier/ 2-time world champion
- David Spade - comedian,
- Kate Spade - fashion designer
- Stefan Springman television producer and host of the VH1 show Can't Get a Date
- Paul Spudis - geologist and lunar scientist
- Phillippi Sparks - former NFL player, member Sigma Chi
- Brenda Strong - actress
- Terrell Suggs - NFL player
- Pat Tillman - former NFL player; US Army Corporal
- Andrew Walter - NFL player
- Fee Waybill - Performer, Lead Singer of The Tubes (band)
- Danny White - College Football Hall of Fame member, former NFL quarterback, and former Arizona Rattlers coach
- Darren Woodson - former NFL player, ESPN Analyst
- Robert Z'Dar - actor
- Danielle Ammaccapane - Professional golfer
- Joe Shoen - Chairman, Amerco/Chairman and President, U-Haul
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