Indium(III) selenide
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Indium(III) selenide | |
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IUPAC name | Indium(III) selenide |
Other names | indium selenide, indium sesquiselenide |
Identifiers | |
CAS number | [12056-07-4] |
Properties | |
Molecular formula | In2Se3 |
Molar mass | 466.516 g/mol |
Appearance | black crystalline solid |
Density | 5.80 g/cm³ |
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references |
Indium(III) selenide is a compound of indium and selenium. It has potential for use in photovoltaic devices and it has been the subject of extensive research. The two most common forms α- and β- have defect wurtzite structures, however there are five known forms (α, β, γ, δ, κ)[1] The α- β phase transition is accompanied by a change from metallic conduction. [2] The band-gap of γ-In2Se3 is approximately 1.9 eV. The crystalline form of a sample can depend on the method of production, for example thin films of pure γ-In2Se3 have been produced from trimethylindium, InMe3, and hydrogen selenide, H2Se, using MOCVD techniques [3]
[edit] See also
[edit] General References
Greenwood, N. N.; Earnshaw, A. (1997). Chemistry of the Elements, 2nd Edition, Oxford:Butterworth-Heinemann. ISBN 0-7506-3365-4.
[edit] Footnotes
- ^ Crystal structure of κ-In2Se3. Jasinski, J.; Swider, W.; Washburn, J.; Liliental-Weber, Z.; Chaiken, A.; Nauka, K.; Gibson, G. A.; Yang, C. C.Applied Physics Letters, Volume 81, Issue 23, id. 4356 (2002) 10.1063/1.1526925
- ^ Some Electrical and Optical Properties of In2Se3 D. Bidjin, S. Popovi , B. Elustka Physica Status Solidi (a) Volume 6, Issue 1 , Pages 295 – 299 DOI 10.1002/pssa.2210060133
- ^ Growth of single-phase In2Se3 by using metal organic chemical vapor deposition with dual-source precursors Chang, K. J.; Lahn, S. M.; Chang, J. Y. Applied Physics Letters, Volume 89, Issue 18, id. 182118 (3 pages) (2006). DOI: 10.1063/1.2382742