Dimethylbenzylamine

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Dimethylbenzylamine
IUPAC name N,N-dimethyl-1-phenylmethanamine
Other names N,N-Dimethylbenzenemethanamine, N-Benzyldimethylamine, Dimethylbenzylamine, Benzyl-N,N-dimethylamine, N-(Phenylmethyl)dimethylamine, BDMA, Sumine 2015, Benzenemethanamine, Dabco B-16, Araldite accelerator 062, N,N-Dimethyl(phenyl)methanamine
Identifiers
CAS number [103-83-3]
PubChem 7681
EINECS number 203-149-1
SMILES CN(C)Cc1ccccc1
InChI 1/C9H13N/c1-10(2)8-9-6-4-3-5-7-9/h3-7H,8H2,1-2H3
Properties
Molecular formula C9H13N
Molar mass 135.21 g/mol
Appearance colourless to yellow liquid
Density 0.91 g/cm3 at 20 °C
Melting point

-75 °C

Boiling point

180 - 183 °C

Solubility in water 1.2 g/L (27 °C)
Hazards
NFPA 704
2
3
0
 
R-phrases R10, R20, R21, R22, R34, R52, R53
S-phrases S26, S36, S45, S61
Flash point 55 °C
Autoignition
temperature
410 °C
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox disclaimer and references

Dimethylbenzylamine is the organic compound with the formula C6H5CH2N(CH3)2. The molecule contains the benzyl group, C6H5CH2, attached to a dimethylamino functional group. It is used as a catalyst for the formation of polyurethane foams and epoxy resins.

Like some other benzyl compounds, the molecule is undergoes directed ortho metalation with butyl lithium. Because of this reaction, many derivatives are known with the formula 2-X-C6H4CH2N(CH3)2 (X = SR, PR2, etc).

The amine is basic and undergoes quaternization with methyl iodide to give the ammonium salt [C6H5CH2N(CH3)3]+I-.[1] Such salts are useful phase transfer catalysts.

[edit] See also

[edit] References

  1. ^ Brasen, W. R.; Hauser, C. R. (1963). "2-Methylbenzyldimethylamine". Organic Syntheses Coll. 4: 585. 

[edit] External links