Talk:Chichibabin reaction

From Wikipedia, the free encyclopedia

WikiProject Chemistry This article is within the scope of WikiProject Chemistry, which collaborates on Chemistry and related subjects on Wikipedia. To participate, help improve this article or visit the project page for details on the project.

Article Grading: The article has not been rated for quality and/or importance yet. Please rate the article and then leave comments here to explain the ratings and/or to identify the strengths and weaknesses of the article..

[edit] Substitution pattern confusion

"The reaction takes place especially in 2 and 5 position of the Pyridine."

By resonance stability rules, I would expect 2 (==6) and 4 to be the pair with similar reactivity, and different than 3 (==5). Is something special going on here?

"As electrophilic addition is only possible in 3 and 5 position of the pyridine ring the 2 and 5 positions became available for further synthesis by the Chichibabin reaction" is confusing. First part contradicts previously quoted sentence (though matches that 3==5 is a consistent set in my comment). But more, what is this whole sentence actually saying? I can't deciper what does happen (normally), what happens when that does not happen, or what prevents the normal from happening. DMacks (talk) 18:50, 30 January 2008 (UTC)

Right! I reworded it and tried to be more precise.--Stone (talk) 21:24, 30 January 2008 (UTC)

I rephrased the sentence once again, because it still looked very confusing to me. I also added a reaction mechanism image from the German article. However it presumably contains a mistake -- the reaction temperature cannot be 100-200 degrees C (unless you apply pressure), as the reaction takes place in liquid ammonia. 217.230.185.68 (talk) 22:02, 5 March 2008 (UTC)