Carbon dioxide equivalent
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Carbon dioxide equivalent (CDE) and Equivalent carbon dioxide (or CO2e) are two related but distinct measures for describing how much global warming a given type and amount of greenhouse gas may cause, using the functionally equivalent amount or concentration of carbon dioxide (CO2) as the reference.
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[edit] Equivalent carbon dioxide
Equivalent CO2 (CO2e) is the concentration of CO2 that would cause the same level of radiative forcing as a given type and concentration of greenhouse gas. Examples of such greenhouse gases are methane, perfluorocarbons and nitrous oxide. CO2e is expressed as parts per million by volume, ppmv.
- CO2e calculation example:
- The radiative forcing for pure CO2 is approximated by RF = αln(C / C0) where C is the present concentration, α is a constant, 5.35 and C0 the pre-industrial concentration, 278 ppm. Hence the value of CO2e for an arbitrary gas mixture with a known radiative forcing is given by C0exp(RF / α) in ppmv.
- To calculate the radiative forcing for a 1998 gas mixture, IPCC 2001 gives the radiative forcing (relative to 1750) of various gases as: CO2=1.46 (corresponding to a concentration of 365 ppmv), CH4=0.48, N2O=0.15 and other minor gases =0.01 W/m2. The sum of these is 2.10 W/m2. Inserting this to the above formula, we obtain CO2e = 412 ppmv.
[edit] Carbon dioxide equivalent
Carbon dioxide equivalency is a quantity that describes, for a given mixture and amount of greenhouse gas, the amount of CO2 that would have the same global warming potential (GWP), when measured over a specified timescale (generally, 100 years). Carbon dioxide equivalency thus reflects the time-integrated radiative forcing, rather than the instantaneous value described by CO2e.
The carbon dioxide equivalency for a gas is obtained by multiplying the mass and the GWP of the gas. The following units are commonly used:
- By the UN climate change panel IPCC: billion metric tonnes of CO2 equivalent (GtCO2eq).
- In industry: million metric tonnes of carbon dioxide equivalents (MMTCDE).
- For vehicles: g of carbon dioxide equivalents / km (gCDE/km).
For example, the GWP for methane is 21 and for nitrous oxide 310. This means that emissions of 1 million metric tonnes of methane and nitrous oxide respectively is equivalent to emissions of 21 and 310 million metric tonnes of carbon dioxide.
[edit] See also
[edit] References
- Gohar and Shine, Equivalent CO2 and its use in understanding the climate effects of increased greenhouse gas concentrations, Weather, Nov 2007, p307-311.