Calcium silicate

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Calcium silicate
Image:Calcium silicate.png
IUPAC name Calcium silicate
Other names silicic acid calcium salt, grammite, silene, micro-cell
Identifiers
CAS number [1344-95-2]
Properties
Molecular formula Ca2SiO4
Molar mass 172.2391 g/mol
Appearance White or cream powder
Melting point

°C (? K)
Boiling point

°C (? K)
Hazards
MSDS External MSDS
Main hazards Irritant
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)
Infobox disclaimer and references

Calcium silicates are a set of four compounds obtained by reacting calcium oxide and silica in various ratios[1]. These have compositions Ca3O.SiO4, Ca2SiO4, Ca3Si2O7 and CaSiO3. Calcium orthosilicate is a white powder with the chemical formula Ca2SiO4. It has a low bulk density and high physical water absorption. It is used as an anti-caking agent and an antacid. A white free-flowing powder derived from limestone and diatomaceous earth, calcium silicate has no known adverse effects to health. It is used in roads, insulation, bricks, and roof tiles.

Contents

[edit] High temperature insulation

Industrial grade piping and equipment insulation is often fabricated from calcium silicate. Its fabrication is a routine part of the curriculum for insulation apprentices. Calcium silicate competes in these realms against rockwool as well as proprietary insulation solids, such as perlite mixtures and vermiculite bonded with sodium silicate.

[edit] Passive fire protection

Circuit integrity fireproofing of cable trays in Lingen/Ems, Germany using calcium silicate board system qualified to DIN 4102. Other methods for exterior protection of electrical circuits include boards made of sodium silicate bonded and pressed vermiculite and flexible wraps made of ceramic fibre and rockwool.
Circuit integrity fireproofing of cable trays in Lingen/Ems, Germany using calcium silicate board system qualified to DIN 4102. Other methods for exterior protection of electrical circuits include boards made of sodium silicate bonded and pressed vermiculite and flexible wraps made of ceramic fibre and rockwool.

One of the most successful materials in fireproofing in Europe is calcium silicate. Where North Americans use spray fireproofing plasters, Europeans are more likely to use cladding made of calcium silicate. Calcium silicate is easily damaged by water. Therefore, silicone treated sheets are available to fabricators to mitigate potential harm from high humidity or general presence of water. Fabricators and installers of calcium silicate in passive fire protection often also install firestops.

[edit] Calcium silicate in the steel industry

It is also a constituent of the slag that is produced when molten iron is made from iron ore and calcium carbonate in a blast furnace.

[edit] As a product of sealants

When sodium silicate is applied as a sealant to cured concrete or the shells of fresh eggs, it chemically reacts with calcium hydroxide or carbonate to form calcium silicate hydrate, sealing pores with a relatively impermeable material.

[edit] References

  1. ^ H F W Taylor, Cement Chemistry, Academic Press, 1990, ISBN 0-12-683900-X, p 33-34

[edit] See also

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