Butanone
From Wikipedia, the free encyclopedia
 |
This article does not cite any references or sources. (October 2007) Please help improve this article by adding citations to reliable sources. Unverifiable material may be challenged and removed. |
| Butanone | |
|---|---|
 |
|
 |
|
| Other names | Methyl ethyl ketone (MEK); Methylpropanone; Ethylmethylketone |
| Identifiers | |
| CAS number | [78-93-3] |
| RTECS number | EL6475000 |
| SMILES | CCC(=O)C |
| Properties | |
| Molecular formula | C4H8O CH3(CO)C2H5 |
| Molar mass | 72.11 g/mol |
| Appearance | Colorless liquid |
| Density | 0.8050 g/cm³, liquid |
| Melting point |
−86 °C (187 K) |
| Boiling point |
80 °C (353 K) |
| Solubility in water | 29 g/100 ml (20 °C) |
| Viscosity | 0,43 cP at 20 °C |
| Structure | |
| Dipole moment | 2.76 D |
| Hazards | |
| MSDS | External MSDS |
| EU classification | Flammable (F) Irritant (Xi) |
| NFPA 704 |
 3
1
0
|
| R-phrases | R11, R36, R66, R67 |
| S-phrases | (S2), S9, S16 |
| Flash point | −9 °C |
| Autoignition temperature |
505 °C |
| Related compounds | |
| Related Ketones | Acetone; 3-pentanone; 3-Methylbutanone |
| Supplementary data page | |
| Structure and properties |
n, εr, etc. |
| Thermodynamic data |
Phase behaviour Solid, liquid, gas |
| Spectral data | UV, IR, NMR, MS |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references |
|
Butanone is a manufactured organic chemical. It is a colorless liquid with a sharp, sweet butterscotch odor reminiscent of acetone. It is a ketone, also known as methyl ethyl ketone (MEK).
Butanone is produced in large quantities. Nearly half of it is used in paints and other coatings because it will quickly evaporate. It dissolves many substances and is used as a solvent in processes involving gums, resins, cellulose acetate and nitrocellulose coatings and in vinyl films. It is also used in the synthetic rubber industry, It is used in manufacturing plastics, textiles, in the production of paraffin wax, and in household products such as lacquer, varnishes, paint remover, a denaturing agent for denatured alcohol, glues and as a cleaning agent. MEK is also used in dry erase markers as the solvent of the erasable dye. It is used for synthesis of methyl ethyl ketone peroxide, a catalyst for some polymerization reactions. It is highly flammable. It is not considered a large health threat.
Butanone occurs as a natural product. It is made by some trees and found in some fruits and vegetables in small amounts. It is also released to the air from car and truck exhausts.
[edit] Health effects
The known health effects to people from exposure to butanone are slight irritation of the nose, throat, skin, and eyes. There are no known cases of any humans dying from breathing butanone alone. It is basically harmless. However, if butanone is breathed along with other chemicals that damage health, it can increase the amount of damage that occurs.
Serious health effects in animals have been seen only at very high levels. When breathed, these effects included birth defects (Schwetz et al. 1991. Fund. Appl. Toxicol. 16:742-748), loss of consciousness, and death. When swallowed, rats had nervous system effects including drooping eyelids and uncoordinated muscle movements. There was no damage to the ability to reproduce. Mice who breathed low levels for a short time showed temporary behavioral effects. Mild kidney damage was seen in animals that drank water with low levels of butanone for a short time.
There are no long-term studies with animals either breathing or drinking butanone.
Methyl ethyl ketone is listed as a Table II precursor under the United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances[1].
