Bromochloromethane

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Bromochloromethane
IUPAC name Bromochloromethane
Other names Monochloromonobromomethane, Bromo(chloro)methane, Chloromethyl bromide, Methylene chlorobromide, Methylene bromochloride, Borothene, Halon 1011, BCM, CBM, UN 1887
Identifiers
CAS number [74-97-5]
PubChem 6333
EINECS number 200-826-3
KEGG C02661
ChEBI 17194
RTECS number PA5250000
SMILES C(Cl)Br
InChI 1/CH2BrCl/c2-1-3/h1H2
Properties
Molecular formula CH2BrCl
Molar mass 129.38 g/mol
Appearance Colorless to yellow liquid with chloroform-like odor
Density 1.9344 g/cm3 at 20 °C
Melting point

-86.5 °C

Boiling point

68.1 °C

Solubility in water 16.7 g/l
Vapor pressure 15.6 kPa at 20 °C
Hazards
R-phrases R37, R38, R41, R59
S-phrases S26, S39, S59
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox disclaimer and references

Bromochloromethane or methylene bromochloride and Halon 1011 is a mixed halomethane. It is a heavy low-viscose liquid with refractive index 1.4808.

It was used in fire extinguishers, but due to its ozone depletion potential was its production banned from the 1st January 2002 at the Eleventh Meeting of the Parties for the Montreal Protocol on Substances that Deplete the Ozone Layer.

It can be biologically decomposed using hydrolase enzyme alkylhalidase (EC 3.8.1.1) by reaction:

CH2BrCl + H2O = CH2O + Br2 + Cl2.

[edit] In fiction

In the Enter the Matrix video game, the player can find a "Chloro-Bromo Methane Gun", which is used as a fire extinguisher. It fires a pressurized cartridge of CBM gas to put out fires. However, due to its chemical properties, firing a cartridge near people causes their lungs to fill with liquid, effectively drowning them.

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