Baudisch reaction

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The Baudisch Reaction was discovered by Baudish in 1939 and further developed by Cronheim. In the reaction a solution containing aqueous hydroxylamine hydrochloride and hydrogen peroxide reacts with benzene or phenol, with the assistance of a copper(II) ion to give o-nitrosophenols.[1] These nitrosophenols can then be used in the manufacture of dyes. [2]

Image:Baudischreaction.png


[edit] References

  1. ^ Maruyama et al., J. Org. Chem. 32, 2516, 2520 (1967)
  2. ^ Encyclopædia Britannica page on dyes

[edit] Other References

  • Baudisch et al., Naturwissenschaften 27, 768, 769 (1939)
  • Baudisch et al.,Science 92, 336 (1940)
  • Baudisch et al.,J. Am. Chem. Soc. 63, 622 (1941)
  • G. Cronheim J. Org. Chem. 12, 1, 7, 20 (1947)
  • Konecny, J. Am. Chem. Soc. 77, 5748 (1955)
  • Maruyama et al., Tettahedron Letters 1966, 5889.

[edit] External links

Source of References


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