Anhydrite

From Wikipedia, the free encyclopedia

Not to be confused with anhydride.
Anhydrite

Anhydrite, Chihuahua, Mexico
General
Category Sulfate mineral
Chemical formula anhydrous calcium sulfate:CaSO4
Identification
Color Colorless, white, bluish white, violet, dark gray
Crystal habit very rare tabular and prismatic crystals. Usually occurs as fibrous, parallel veins that break off into cleavage fragments. Also occurs as grainy, massive, or nodular masses
Crystal system Orthorhombic; 2/m 2/m 2/m
Cleavage [010] Perfect, [100] Perfect, [001] Good
Fracture conchoidal
Mohs Scale hardness 3.5
Luster Vitreous - Pearly
Refractive index nα = 1.567 - 1.574 nβ = 1.574 - 1.579 nγ = 1.609 - 1.618
Optical Properties Biaxial (+)
Birefringence δ = 0.042 - 0.044
Streak white
Specific gravity 2.97
Fusibility 2
Other Characteristics Some specimens fluoresce; many more fluoresce after heating

Anhydrite is a mineral - anhydrous calcium sulfate, CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the orthorhombic barium (baryte) and strontium (celestine) sulfates, as might be expected from the chemical formulas. Distinctly developed crystals are somewhat rare, the mineral usually presenting the form of cleavage masses. The hardness is 3.5 and the specific gravity 2.9. The colour is white, sometimes greyish, bluish or purple. On the best developed of the three cleavages the lustre is pearly, on other surfaces it is vitreous. When exposed to water, anhydrite readily transforms to the more commonly occurring gypsum, (CaSO4·2H2O) by the absorption of water. Anhydrite is commonly associated with calcite, halite, and sulfides such as galena, chalcopyrite, molybdenite and pyrite in vein deposits.

Anhydrite is most frequently found in evaporite deposits with gypsum; it was, for instance, first discovered, in 1794, in a salt mine near Hall in Tirol. In this occurrence depth is critical since nearer the surface anhydrite has been altered to gypsum by absorption of circulating ground water.

From an aqueous solution calcium sulfate is deposited as crystals of gypsum, but when the solution contains an excess of sodium or potassium chloride anhydrite is deposited if temperature is above 40°C. This is one of the several methods by which the mineral has been prepared artificially, and is identical with its mode of origin in nature, the mineral is common in salt basins.

The name anhydrite was given by A. G. Werner in 1804, because of the absence of water of crystallization, as contrasted with the presence of water in gypsum. Some obsolete names for the species are muriacite and karstenite; the former, an earlier name, being given under the impression that the substance was a chloride (muriate). A peculiar variety occurring as contorted concretionary masses is known as tripe-stone, and a scaly granular variety, from Vulpino, near Bergamo, in Lombardy, as vulpinite; the latter is cut and polished for ornamental purposes.

[edit] Chicken-wire anhydrite

Chicken-wire anhydrite is a type of anhydrite deposit where seeping ground water gradually deposited large amounts of anhydrite in the sediment, replacing most of it, so that a cross-section of it looks somewhat like the coarse wire netting often used to confine poultry.

[edit] References